Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Calculate Z, HR, and SR by the Peng/Robinson equation for benzene at 575 K and 30 bar, and compare the results with values found from suitable generalized correlations.
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- :) Using the ideal gas model, show that () (), ӘР ЭТ T V =-1arrow_forward(a)Using the compressibility chart, determine the compression factor (Z). Express your final answers in 3 significant figures (b)What would be the corresponding state of carbon dioxide? (Pc = 72.9 atm, Tc = 304.2 K) T (K) 200 P (atm) Tс (К) Pc (atm) Gas Argon 23.0 150.7 48.0 1.1 1.0 T- 2.00 0.9 I=1.50 0.8 Tx =1.30 0.7 to 0.6 T=1.20 0.5 T-1.10 0.4 Legend: X Methane O Ethylene A Ethane O Propane O n-Butane Iso-pentane • n-Heptane A Nitrogen T =1.00 0.3 Carbon dioxide Water 0.2 Average curve based on data on hydrocarbons 0.1 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 Reduced pressure P x of xarrow_forwardPHYSICAL CHEMISTRY:Calculate the pressure exerted by 1.0 mol C2H6 at 1000 K in 100 cm3 using (a) the ideal gas equation and (b) the van der Waals equation. The van der Waals constant for C2H6 are: a = 5.562 bar dm6 mol-2 ; b = 0.06380 dm3 mol-1 answer:[831; 1.72 x 10-3]arrow_forward
- Calculate the fugacity of dry ice (CO₂ ice) at the triple point (T=216.55 °K, P-5.12673 bar). Assume that the thermal properties of the vapor phase of carbon dioxide are described by the Peng-Robinson equation of state. Express your result in bar and and round your numerical answer to one decimal digit.arrow_forwardConsider cyclohexane at 175ºC. Determine Z and V (cm^3/mol) when P = 8.74 bar (saturated liquid)arrow_forwardThe following equation of state is found to describes the behavior of a particular gas with reasonable accuracy. Z = 1 + (a - b/T)P/RT where a=15x10-6 m3/mol and b= 0.06 (m3.K)/mol. Show that the residual enthalpy and residual entropy take the form: (H^r)/RT =(A-2B) and (S^r)/R = -B where A =(aP)/RT and B = (bP)/(RT^2)arrow_forward
- How many intensive variables are necessary to completely specify the state of pure water and pure glycerol at temperatures above 18 degrees C. What are they? If the pressure is fixed at 1 bar, how many intensive variables are necessary?arrow_forwardSketch very roughly the phase diagrams for water and carbon dioxide and use them to answer this question: at a pressure of X atmospheres and a temperature Y degrees Kelvin,what is the phase of water, and what is the phase of carbon dioxide Y=9.43 X=943arrow_forward
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