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Chemistry
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ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Calculate the standard reaction potential and use the half-reaction method to determine the moles of electrons per reaction.
2Au3+(aq) + 3Zn(s) --> 2Au(s) + 3Zn2+(aq)
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- A chemist designs a galvanic cell that uses these two half-reactions: half-reaction standard reduction potential CrO2−4 (aq)+4H2O(l)+3e−→ CrOH3(s)+5OH−(aq) =E0red−0.13V Cl2(g)+2e−→ 2Cl−(aq) =E0red+1.359V Answer the following questions about this cell. Write a balanced equation for the half-reaction that happens at the cathode. Write a balanced equation for the half-reaction that happens at the anode. Write a balanced equation for the overall reaction that powers the cell. Be sure the reaction is spontaneous as written. Do you have enough information to calculate the cell voltage under standard conditions? If you said it was possible to calculate the cell voltage, do so and enter your answer here. Be sure your answer has the correct number of significant digits. Varrow_forwardUse the following standard reduction potentials to determine which species is the strongest oxidizing agent. Fe2+(aq) + 2 e– → Fe(s); E° = –0.41 V Pt2+(aq) + 2 e– → Pt(s); E° = 1.18 V Cr2O72–(aq) + 14 H+(aq) + 6 e– → 2 Cr3+(aq) + 7 H2O(); E° = 1.33 V Which of the following is the strongest oxidizing agent? Fe Pt Cr^3+ Fe^2+ Cr2O7^2-arrow_forwardCalculate the standard cell potential and note whether the reaction is spontaneous under standard conditions. Mg(s) + Cu2+ --> Mg2+ + Cu(s)arrow_forward
- A galvanic (voltaic) cell consists of an electrode composed of manganese in a 1.01.0 M manganese(II) ion solution and a second electrode composed of lead in a 1.01.0 M lead(II) ion solution, connected by a salt bridge. Calculate the standard potential for this cell at 25 ∘C25 ∘C. Use this list of standard reduction potentials.arrow_forwardUsing standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy following redox reaction. Be sure your answer has the correct number of significant digits. ■ 10Fe²+ (aq) +2103 (aq) +12H* (aq) → 10Fe³ KJ 10Fe³+ (aq) + ¹₂ (s) + 6H₂O (1) x10 X Ś AGO for the ? olo 18 Ararrow_forwardUsing standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy AG for the following redox reaction. Round your answer to 2 significant digits. 2Cr(OH)3 (s) +100H¯ (aq) +3Zn²+ (aq) → 2CrO²¯ (aq) +8H₂O (1) + 3 Zn (s) 0 x10 Xarrow_forward
- Using standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy ΔG^0 for the following redox reaction. 2Br-(aq) + 2H2O(l) -> Br2(l) + H2(g) + 2OH−(aq) Be sure your answer has the correct number of significant digitssarrow_forwardUse standard reduction potentials to calculate the standard free energy change in kJ for the reaction: (aq) + 2Cu+ (aq) → Pb(s) + 2Cu²+ (aq) AG° Pb²+ = Pb²+ (aq) + 2e¯ → Pb(s) Ee = -0.126 V red 2+ Cu²+ (aq) + e → Cu+ (aq) Fº red kJ K for this reaction would be = = 0.153 V + than one.arrow_forwardUsing standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy AG° for the following redox reaction. Round your answer to 3 significant digits. 6CI (aq)+2Cr0 (aq)+8H,0 (1) → 3Cl, (g)+2Cr(OH), (s) + 10OH (aq)arrow_forward
- Use standard reduction potentials to calculate the equilibrium constant for the reaction: 2+ Cu²+ (aq) + 21 (aq) → Cu(s) + I₂ (s) From the table of standard reduction potentials: Cu²+/Cu 0.337 V, E₁₂/1 Hint: Carry at least 5 significant figures during intermediate calculations to avoid round off error when taking the antilogarithm. Equilibrium constant at 298 K:I AGO for this reaction would be than zero. = = 0.535 Varrow_forwardConsider the following standard reduction potentials: Zn2*(aq) + 2 e → Zn(s) E° = -0.76 V Mg2*(aq) + 2 e → Mg(s) E° = -2.37 V Ag*(aq) + e → Ag(s) E° = +0.80 V Which is the strongest oxidizing agent? Mg2*(aq) Zn2*(aq) Ag*(aq) 5:08 PM 90°F Partly sunny P Type here to search 8/6/2021arrow_forwardA voltaic cell is constructed in which the cathode is a standard hydrogen electrode and the anode is a hydrogen electrode (pH2)= 1atm) immersed in a solution of unknown [H+]. If the cell potential is 0.200 V, what is the pH of the unknown solution at 298 K?arrow_forward
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