Calculate the standard cell potential at 25°C for the following cell reaction from standard free energies of formation: 2A1(s) + 3H&²+ (ag) → 2Al** (aq) + 3Hg(!)

Fundamentals Of Analytical Chemistry
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Chapter19: Applications Of Standard Electrode Potentials
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Problem 19.8QAP
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Calculate the standard cell potential at 25°C for the following cell reaction from standard free energies of formation:
2Al(s) + 3H3²+ (aq) → 2A1š+ (ag) + 3Hg(1)
Standard Free Energy of Formation
Ion
AG; (kJ/mol)
Als+ (aq)
-485.0
Zn2+ (aq)
-147.0
Co2+ (ag)
-54.4
Ni²+ (ag)
-45.6
Pb?+ (ag)
-24.39
Cu²+ (ag)
65.52
Hg²+ (aq)
164.4
Fe?+ (ag)
-78.87
Standard cell potential
V
Transcribed Image Text:Calculate the standard cell potential at 25°C for the following cell reaction from standard free energies of formation: 2Al(s) + 3H3²+ (aq) → 2A1š+ (ag) + 3Hg(1) Standard Free Energy of Formation Ion AG; (kJ/mol) Als+ (aq) -485.0 Zn2+ (aq) -147.0 Co2+ (ag) -54.4 Ni²+ (ag) -45.6 Pb?+ (ag) -24.39 Cu²+ (ag) 65.52 Hg²+ (aq) 164.4 Fe?+ (ag) -78.87 Standard cell potential V
Calculate the standard cell potential of the cell corresponding to the oxidation of oxalic acid,
H2 C204, by chlorate ion,
ClO3 (ag).
3H2C204(aq) + ClO3 (ag) → 6CO2 (g) + Cl¯ (ag) + 3H2O(1)
AG; for
H2 C204 (aq) is -698 kJ.
You
may
need to use the following data.
Substance or ion AG; (kJ/mol)
ClO3 (ag)
-292.3
CO2 (g)
-394.4
Cl" (aq)
-131.3
H2O(1)
-237.1
Standard cell potential =
V
Transcribed Image Text:Calculate the standard cell potential of the cell corresponding to the oxidation of oxalic acid, H2 C204, by chlorate ion, ClO3 (ag). 3H2C204(aq) + ClO3 (ag) → 6CO2 (g) + Cl¯ (ag) + 3H2O(1) AG; for H2 C204 (aq) is -698 kJ. You may need to use the following data. Substance or ion AG; (kJ/mol) ClO3 (ag) -292.3 CO2 (g) -394.4 Cl" (aq) -131.3 H2O(1) -237.1 Standard cell potential = V
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