Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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**Title: Understanding Pressure Calculations for CCl₄ Using Ideal and Van der Waals Equations**

**Objective:**
Calculate the pressure exerted by CCl₄ at 80°C with the following conditions: 1.00 mol occupying 33.3 L. Consider both ideal and van der Waals scenarios.

**Key Tasks:**

**1. Pressure Calculation Using the Ideal Gas Equation:**
- **Formula:** PV = nRT
- **Variables:**
  - P = Pressure
  - V = Volume (33.3 L)
  - n = Number of moles (1.00 mol)
  - R = Ideal gas constant
  - T = Temperature in Kelvin (80°C)

**2. Pressure Calculation Using the Van der Waals Equation:**
- **Formula:** \((P + \frac{an^2}{V^2})(V - nb) = nRT\)
- **Variables:**
  - a, b = Van der Waals constants specific to CCl₄
  - Refer to Table 10.3 for values of a and b.

**3. Deviation from Ideal Behavior Analysis:**
- Consider which substance, Cl₂ or CCl₄, is expected to deviate more from ideal gas behavior under these conditions.
- Provide an explanation based on molecular interactions and size. 

**Learning Outcomes:**
- Explore how real gases differ from ideal gases.
- Understand the applicability of the van der Waals equation for different gases.
- Evaluate deviations based on intermolecular forces and molecular size differences.

---

This structured approach allows students to analyze gas pressures using theoretical and practical models, enhancing comprehension of gas behaviors under various conditions.
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Transcribed Image Text:**Title: Understanding Pressure Calculations for CCl₄ Using Ideal and Van der Waals Equations** **Objective:** Calculate the pressure exerted by CCl₄ at 80°C with the following conditions: 1.00 mol occupying 33.3 L. Consider both ideal and van der Waals scenarios. **Key Tasks:** **1. Pressure Calculation Using the Ideal Gas Equation:** - **Formula:** PV = nRT - **Variables:** - P = Pressure - V = Volume (33.3 L) - n = Number of moles (1.00 mol) - R = Ideal gas constant - T = Temperature in Kelvin (80°C) **2. Pressure Calculation Using the Van der Waals Equation:** - **Formula:** \((P + \frac{an^2}{V^2})(V - nb) = nRT\) - **Variables:** - a, b = Van der Waals constants specific to CCl₄ - Refer to Table 10.3 for values of a and b. **3. Deviation from Ideal Behavior Analysis:** - Consider which substance, Cl₂ or CCl₄, is expected to deviate more from ideal gas behavior under these conditions. - Provide an explanation based on molecular interactions and size. **Learning Outcomes:** - Explore how real gases differ from ideal gases. - Understand the applicability of the van der Waals equation for different gases. - Evaluate deviations based on intermolecular forces and molecular size differences. --- This structured approach allows students to analyze gas pressures using theoretical and practical models, enhancing comprehension of gas behaviors under various conditions.
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