Calculate the potential (emf) of a working galvanic cell that is based on these two half cells and standard potentials (both written as reduction reactions) in an aqueous basic solution. Cr3+(aq)  →  Cr2+(aq)       E°(Cr3+/Cr2+) = −0.40 V IO−(aq)  →  I2(aq)            E°( IO−/I2) = +1.60 V The pH of this cell is 14, and the concentrations of species are:  Cr3+ is 0.5 M, Cr2+is 0.2 M, IO− is 0.5 M and I2 is 0.8 M.

Fundamentals Of Analytical Chemistry
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Chapter19: Applications Of Standard Electrode Potentials
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Calculate the potential (emf) of a working galvanic cell that is based on these two half cells and standard potentials (both written as reduction reactions) in an aqueous basic solution.

Cr3+(aq)  →  Cr2+(aq)       E°(Cr3+/Cr2+) = −0.40 V

IO(aq)  →  I2(aq)            E°( IO/I2) = +1.60 V

The pH of this cell is 14, and the concentrations of species are:  Cr3+ is 0.5 M, Cr2+is 0.2 M, IO is 0.5 M and I2 is 0.8 M.

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