
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Calculate the pH of cathode half-cell solution if the cell emf at 298 K is measured to be +0.684 V when [Zn2+]=0.30 M and Ph2=0.90 atm
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- A galvanic cell is constructed as follows. One half-cell consists of a platinum wire immersed in a solution containing 1.00 M Sn2+ and 1.00 M Sn4+. The other half-cell has a thallium rod immersed in a solution of 1.00 M Tl+. What is the equilibrium constant at 25° C?(Eo= Tl+ / Tl = −0.34 V.)? What is the cell voltage if the Tl+ concentration is increased 6−fold?arrow_forwardA galvanic cell was constructed with a nickel electrode that was dipped into 1.1 M NiSO4 solution and a chromium electrode that was immersed into a solution containing Cr3+ at an unknown concentration. The potential of the cell was measured to be 0.557 V, with the chromium serving as the anode. The standard cell potential for this system was determined to be 0.487 V. What was the concentration of Cr3+ in the solution of unknown concentration?arrow_forwardCalculate the cell potential for the galvanic cell in which the given reaction occurs at 25 °C, given that [Nit] = 0.00170 M and [Au] = 0.868 M. Standard reduction potentials can be found in this table. %3D 3 Ni(s) + 2 Au*(aq) 3 Ni?+(aq) + 2 Au(s) E = Varrow_forward
- Calculate Kp for calcium sulfate, CaSO4, given that the cell potential at 25 °C for the following concentration cell is +0.0772 V. Pt(s) CaSO4(saturated solution)||Ca(N03)2(2.86 M)||Pt(s)arrow_forwardThe free energy change for the following reaction at 25 °C, when [Cr**]= 2.80×103 M and [H= 1.11 M, is 94.0 kJ: 2Cr*(2.80×10³ M) + H,(g)2Cr*(aq) + 2.00H*(1.11 M) AG = 94.0 kJ What is the cell potential for the reaction as written under these conditions? Answer: V Would this reaction be spontaneous in the forward or the reverse direction?arrow_forwardGibbs free energy= -434250 J/mol for a galvanic cell whose two half-reactions: Mt3+ (aq) + 3 e1- → Mt (s), and R2+ (aq) + 2 e1- → R (s), have standard reduction potentials of 1.09 V and 0.34 V respectivelyarrow_forward
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