Calculate the IHD and explain (elucidate) the structure using the 1H and 13C NMR data.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Calculate the IHD and explain (elucidate) the structure using the 1H and 13C NMR data.

1. ¹H-NMR C₂H₂NO
Assign.
9
ABCDE
-00
8
Shift (ppm)
7.786
7.447
7.366
6.98
2.952
7
()
5
ppm
- M
3
-N
2
1
Hz
ppm
3118.53 7.804
3116.58 7.799
3115.36 7.796
3114.01 7.792
3110.35 7.783
3108.28 7.778
3106.81 7.774
2986.82 7.474
2985.47 7.471
2984.25 7.468
2980.35 7.458
2978.27 7.453
2976.07 7.447
2972.17 7.437
2970.83 7.434
2969.48 7.431
2953.00 7.389
2951.17 7.385
2949.58 7.381
2944.70 7.369
2943.36 7.365
2941.89 7.362
2937.87 7.352
2936.16 7.347
2935.18 7.345
2790.16 6.982
1182.01 2.958
1177.25 2.946
Int.
42
245
292
143
97
369
281
39
72
44
53
185
68
96
165
88
54
251
117
205
365
104
67
157
103
36
1000
958
Transcribed Image Text:1. ¹H-NMR C₂H₂NO Assign. 9 ABCDE -00 8 Shift (ppm) 7.786 7.447 7.366 6.98 2.952 7 () 5 ppm - M 3 -N 2 1 Hz ppm 3118.53 7.804 3116.58 7.799 3115.36 7.796 3114.01 7.792 3110.35 7.783 3108.28 7.778 3106.81 7.774 2986.82 7.474 2985.47 7.471 2984.25 7.468 2980.35 7.458 2978.27 7.453 2976.07 7.447 2972.17 7.437 2970.83 7.434 2969.48 7.431 2953.00 7.389 2951.17 7.385 2949.58 7.381 2944.70 7.369 2943.36 7.365 2941.89 7.362 2937.87 7.352 2936.16 7.347 2935.18 7.345 2790.16 6.982 1182.01 2.958 1177.25 2.946 Int. 42 245 292 143 97 369 281 39 72 44 53 185 68 96 165 88 54 251 117 205 365 104 67 157 103 36 1000 958
1. 13C-NMR C₂H₂NO
200
ppm Int.
168.46 174
134.62 196
131.23 474
128.42 930
126.94 1000
26.79 317
180
160
140
120
100
ppm
80
60
40
20
Transcribed Image Text:1. 13C-NMR C₂H₂NO 200 ppm Int. 168.46 174 134.62 196 131.23 474 128.42 930 126.94 1000 26.79 317 180 160 140 120 100 ppm 80 60 40 20
Expert Solution
steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
NMR Spectroscopy of Organic Molecules
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY