
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Calculate (i) the thermal wavelength, (ii) the translational partition function at 300 K and 3000 K of a molecule of molar mass 150 g mol−1 in a container of volume 1.00 cm3.
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- 5. For carbon monoxide at 298K, determine the fraction of molecules in the rotational levels for J=0, 5, 10, 15, and 20. The rotational constant (B) is 3.83x10^-23 Joules.arrow_forwardP31.17 Calculate the rotational partition function for CINO at 500. K where BA 2.84 cm ¹, BB = 0.187 cm¯¹, and Bc 0.175 cm ¹. =arrow_forwardPart A Determine the total molecular partition function for gaseous H2O at 1000. K confined to a volume of 2.20 cm³ . rotational constants for water are BA = 27.8 cm-1, BB = 14.5 cm-1, and Bc = 9.95 cm-1. The vibrational frequencies are 1615, 3694, and 3802 cm-. The ground electronic state is nondegenerate. (Note: the Avogadro's constant NA The 6.022 x 1023 mol-1). Express your answer to three significant figures. Ην ΑΣφ ? 1.29 • 1029 Itotal = Submit Previous Answers Request Answer X Incorrect; Try Again; 5 attempts remainingarrow_forward
- Res translational degrees rotational degrees electronic energetic degrees vibrational degrees Contribution is equal to the theorem's prediction Contribution is not equal to the theorem's predictionarrow_forwardthe rotational constant for 1H35Cl is 10.6 cm-1 . What are the degeneracies, g, of the J=2, and J=3 rotational states?arrow_forwardEvaluate the translational partition function for H2 confined to a volume of 191 cm³ at 328 K . (Note: the Avogadro's constant NA 6.022 x 1023 mol-1). Express your answer to three significant figures. Hν ΑΣφ ? qT (H2) = 3.17 • 1026 Submit Previous Answers Request Answer X Incorrect; Try Again; 2 attempts remaining Part B Perform the same calculation for N2 under identical conditions. (Hint: Do you need to reevaluate the full expression for qT ?) Express your answer to three significant figures. ? qT (N2) =arrow_forward
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