Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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- On complete combustion at constant pressure, a 1.00-L sample of a gaseous mixture at 0C and 1.00 atm (STP) evolves 75.65 kJ of heat. If the gas is a mixture of ethane (C2H6) and propane (C3H8), what is the mole fraction of ethane in the mixture?arrow_forwardButane gas, C4H10, is sold to campers as bottled fuel. Its density at 25C and 1.00 atm is 2.38 g/L. What volume of butane gas at 25C and 1.00 atm is required to heat one gallon of water (d=1.00g/mL) from 25C to 98C ? The reaction for the combustion of butane (H f =125.6kJ/mol) is C4H10(g)+132 O2(g)4CO2(g)+5H2O(g)arrow_forwardWhat will be the final temperature of a mixture made from equal masses of the following: water at 25.0C, ethanol at 35.5C, and iron at 95C?arrow_forward
- Use the data in Table 2.2 to determine Hp T for Ar at 0C and 1atm. Make any reasonable assumptions necessary.arrow_forwardA refrigerator contains approximately 17cubic feet, or about 480 liters, of air. Assuming it acts as an ideal gas with a molar CV of 12.47 J/mol.K, what is the change in U in cooling the air from normal room temperature 22C to refrigerator temperature 4C? Assume an initial pressure of 1.00 atm.arrow_forwardCalculate H when a 38-g sample of glucose, C6H12O6(s), burns in excess O2(g) to form CO2(g) and H2O() in a reaction at constant pressure and 298.15 K.arrow_forward
- Carbon monoxide poisoning results when carbon monoxide replaces oxygen bound to hemoglobin. The oxygenated form of hemoglobin, HbO2 carries O2 to the lungs. HbO2(aq)+CO(g)HbCO(aq)+O2(g) At 98.6°F (37°C), G° for the reaction is about -14 kJ. What is the ratio of [HbO2] to [HbCO] when the pressure of CO is the same as that of O2?arrow_forwardConsider the reaction between methane and oxygen producing carbon dioxide and water. Suppose that the reaction is carried out in a furnace used to heat a house. If q=890kJ and w=+5kJ, what is E? H at 25C?arrow_forwardWhich of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forward
- Use the data in Table 2.2 to determine PH T for N2 at 50C and 20atm. Make any reasonable assumptions necessary.arrow_forwardConsider a mixture of air and gasoline vapor in a cylinder with a piston. The original volume is 40. cm3. If the combustion of this mixture releases 950. J of energy, to what volume will the gases expand against a constant pressure of 650. torr if all the energy of combustion is converted into work to push back the piston?arrow_forwardCalculate G and G at 303 C for the following equation. CO(g, 2 atm) + Cl2 (g, 1 atm) COCl2(g, 0.1 atm)arrow_forward
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