c) For the following compound identify how many chiral carbons present and how many isomers are possible. ( OH H- CI H H-C-Br d) Figure out elements of unsaturation for the following compound 2. Assign R and S congurations for the following compound. And draw enantiomers and diastereomers -OH CH₂ -Br -H C6H4NOCI

c) For the following compound identify how many chiral carbons present and how many isomers are possible. ( OH H- CI H H-C-Br d) Figure out elements of unsaturation for the following compound 2. Assign R and S congurations for the following compound. And draw enantiomers and diastereomers -OH CH₂ -Br -H C6H4NOCI

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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For the following molecules, draw all possible stereoisomers using line-angle formulas with wedge/dash notation. Label the stereocenters as R or S. Indicate which ones are enantiomers and which ones are diastereomers. (Remember: there are 2 stereoisomers possible for a molecule with n chiral centers) (A) (B) (C) (1 chiral center) Br OH (2 chiral centers) CI OH CH3 (3 chiral centers)
Draw all possible stereoisomers for the following molecule. Indicate which are enantiomers and which are diastereomers and assign absolute chirality at all centers and for all structures. H2N
Classify the following pairs of compounds into a) Connection isomers, b) enantiomers, c) diasteremers, d) the same compound, e) conformations of the same compound.
Assign R- or S-configuration for each chiral center found in the following components. Determine whether each of these molecules is chiral, not chiral, or a meso compound. (i) OH H3C- Cl- ČH3 (ii) CH3 H Br Br- ČH3
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2. Fill in the squares with the correct configuration (R or S) for the following compounds and determine whether they are Enantiomers, Diastereomers, the Same Compound or Constitutional Isomers. Br H₂N NH₂ "Br A) Enantiomers B) Diastereomers C) Same Compour D) Constitutional Isomers
Identify each molecule as Chiral or Achiral. Give explanation
erences) Draw a structural formula of the SR configuration of the compound shown below. CH3 S NR HO Use the wedge/hash bond tools to indicate stereochemistry where it exists. Include H atoms at chiral centers only If a group is achiral, do not use wedged or hashed bonds on it. ood
8) For each of the pairs of molecules drawn below, place letters in the corner boxes corresponding to all accurate descriptions of the relationship between the two molecules. a) b) c) HO F A enantiomers F all letters that apply H H OH Вад CI all letters that apply all letters that apply B diastereomers C different conformations of the same molecule D identical conformations of the same molecule E constitutional isomers F stereoisomers G different molecules H both are chiral I neither is chiral
11. Consider the following compounds: ÇO,H CHO ОНС H. ОНС CO,H H3C- -- H. HO- H3C H. O, H ČOH HO, CH3 B (a) Label the asymmetric carbons as R or S on each compound (A - C). (b) Which compounds, if any, are enantiomers? diastereomers? identical?
2.) For the following 12 compounds, please write the number of chiral centers (0 if there are none) and label each molecule as either chiral or achiral. H3C H3C HO H3C H3C H3C H3C H3C H3C CH3 CH3 OH OH H3C OH OH OH он H3C H,C H3C, H3C H3C OH H3C H3C OH HO H3C но OH OH H3C OH CH3