Bruce is analyzing samples of seawater to measure copper using AAS. The high salt content of the sample matrix is affecting the measurements. What can he do to ensure that the analysis is accurate? Oa Use the method of standard additions, spike a set of samples with known amounts of Copper and extapolate where the calibration curve crosses the x-axis to get the correct value. Ob Rotate the burmer head so that it is perpendicular to the light from the hollow cathode lamp. Oc. Tum down the heat for the air-acetylene flame. Od Use serial dilutions, successively dilute the sample in deionized water. OeUse a different wavelength for analysis.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Please don't provide handwritten solution

 

Bruce is analyzing samples of seawater to measure copper using AAS. The high salt content of the
sample matrix is affecting the measurements. What can he do to ensure that the analysis is accurate?
Oa. Use the method of standard additions, spike a set of samples with known amounts of Copper and extapolate where the
calibration curve crosses the x-axis to get the correct value.
Ob Rotate the burner head so that it is perpendicular to the light from the hollow cathode lamp.
Oc. Turn down the heat for the air-acetylene flame.
Od Use serial dilutions, successively dilute the sample in deionized water.
OeUse a different wavelength for analysis.
Transcribed Image Text:Bruce is analyzing samples of seawater to measure copper using AAS. The high salt content of the sample matrix is affecting the measurements. What can he do to ensure that the analysis is accurate? Oa. Use the method of standard additions, spike a set of samples with known amounts of Copper and extapolate where the calibration curve crosses the x-axis to get the correct value. Ob Rotate the burner head so that it is perpendicular to the light from the hollow cathode lamp. Oc. Turn down the heat for the air-acetylene flame. Od Use serial dilutions, successively dilute the sample in deionized water. OeUse a different wavelength for analysis.
Expert Solution
Step 1: Atomic absorption spectrometry (AAS)

The basic principles of AAS can be expressed as follows. Firstly, all atoms or ions can absorb light at specific, unique wavelengths. When a sample containing copper (Cu) and nickel (Ni), for example, is exposed to light at the characteristic wavelength of Cu, then only the Cu atoms or ions will absorb this light.

Atomic absorption spectrometry (AAS) detects elements in either liquid or solid samples through the application of characteristic wavelengths of electromagnetic radiation from a light source. Individual elements will absorb wavelengths differently, and these absorbances are measured against standards.

steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Analytical Separations
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY