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Within this reaction, provide two accurate sketches (one for Step 1, and the other after Step 2) as shown in the image attached.
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- f. g. OCH 3 CO₂H OCH 3 pyruvic acid 1. SOCI22 2.? NaBH4 CH3OH methicillin (narrow-spectrum, B-lactam antibiotic)? H₂SO4 (cat) C6H8O4 (show structure)1. Hg(OAc)2/THF/H2O ? d) 2. NaBH,ГОн .CO2C2H5 isi ? e)Match set A (common active ingredients of insect repellants) to set B (known properties). Then, match set B to set C (structure). Then, match set C to set A. Set A Set B 1. Citriodiol a. Considered as biopesticide b. Lemon eucalyptus oil c. Gold standard repellant 2. Picaridin 3. DEET 4. Citronellol and Geraniol 5. IR-3535 d. Citronella oil e. Repellant of choice for malarial prevention Set C CH3 а. d. CH3 HO OH H3C CH3 H3C CH3 b. е. с. OH OH
- Draw the structure of the major product of following reactions: CH2l2, Zn(Cu) Et,0 „MgBr H3O* to H,0 2. Zn 3. ..... HCI CH212, Zn(Cu) 4. Et,0 H3O* + CH;CH2M9B. 5,To preview image Click Here Provide the missing major organic products, pay attention to stereochemistry as appropriate. B. C. D. E. Br OH CI 1 CHÍNH 2. LIAH, 3. H₂O* H₂O* 1. Mg/THF 2. CO2 3. H₂O 1. Excess MeMgBr 2. H₂O* 1. SOCI₂ 2. =O OHDraw the organic products formed when CH3CH₂C=C Na reacts with BrCH₂CH₂CH₂CH₂OH. Higher mass product Lower mass product edit structure ... draw structure ...
- compound c compound f Reagents compound e a. HBr m. 2 equivalents of NaNH2 b. HBr, H2O2, hv H2, Lindlar's catalyst Na / NH3 H2SO4, H9SO4 (sia)2BH then H2O2, NaOH n. m c. H2O, H2SO4 d. Br2 e. Cl2 f. H2, Pd g. Br2, H20 h. Cl2, H2O i. O. d. compound b compound d p. q. 1 equivalent of NANH2 r. S. NBS, hv compound a Br2, hy Cl2, hy t. Os04 then NaHSO3 j. Hg(OAc)2, H2O then NaBH4 k. BH3 then H2O2, NaOH I. u. V. HCI w. (CH3)3CO'K* Og then (CH3)2S The above synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. In this synthesis, reagents from the table are used to carry out the indicated steps (shown in blue). In the box below, draw the structure of compound c.IV. Fill-in the missing the reactant, reagent, or major product. 1. Hg(OAc), , H2O 2. NABH, 1. BiologyEnvironmental S 1. OsO4, pyridine 2 NaHSO,, H,O он 3. 2.NH, CH31(excess) aq. Na2CO3 →A A48 "A".... NH, CH3 NH, CH, H,C (1) (2) CH3 CH, NH2 JA) Ph-N(CH) (3) CH, CH3
- Describe what each reagent does in SDS Page 1. Sodiun dodecyl sulfate 2. Polyacrylamide 3. Mercaptoethanol4. Which synthesis, starting from benzene, forms aniline (aminobenzene)? a. 1) HNO3/H₂SO4 b. 1) HNO3/H₂SO4 2) H₂, Pd/C c. 1) NH₂/H₂SO4 d. 1) Cl2, FeCl3 2) NaOH, high T,P e. 1) NH₁/H₂SO4 2) H₂, Pd/CPart 3 out of 4 OTBDMS Mg Br ether protected OH draw structure...