Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Heterolytic Bond Breaking
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Polar Aprotic Solvent
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Oxygen Nucleophiles
Oxygen being an electron rich species with a lone pair electron, can act as a good nucleophile. Typically, oxygen nucleophiles can be found in these compounds- water, hydroxides and alcohols.
Carbon Nucleophiles
We are aware that carbon belongs to group IV and hence does not possess any lone pair of electrons. Implying that neutral carbon is not a nucleophile then how is carbon going to be nucleophilic? The answer to this is that when a carbon atom is attached t…
Question
1. Complete the following equations (asuming that the reactions occur via a bromonium ion). There is no need to write the mechanism. If the reaction produces a pair of enantiomers, draw both structures and assign the stereochemistry (R or S). If the reaction produces a meso compound, you should assign its stereochemistry (R or S), but do not show its enantiomer, since it does not represent a new compound. Clearly label any meso compounds. Note that CH2Cl2 is the solvent, not a reactant. a) Br2 CH,Cl2 b) Br2 CH;Cl, c) Br2 CH,Cl, li
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Transcribed Image Text:1. Complete the following equations (asuming that the reactions occur via a bromonium ion). There is no need to write the mechanism. If the reaction produces a pair of enantiomers, draw both structures and assign the stereochemistry (R or S). If the reaction produces a meso compound, you should assign its stereochemistry (R or S), but do not show its enantiomer, since it does not represent a new compound. Clearly label any meso compounds. Note that CH2Cl2 is the solvent, not a reactant. a) Br2 CH,Cl2 b) Br2 CH;Cl, c) Br2 CH,Cl, li
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