Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Cyclobutane, C4H8, consisting of molecules in which four carbon atoms for a ring, decomposes when heated to give ethylene. C4H8(g) → 2C2H4(g) The reaction is first order. In an experiment, the initial concentration of cyclobutane was (3.500x10^-3) M. After heating at 450 °C, for (5.55x10^2) s, this was reduced to (2.6090x10^-3) M. What was the concentration of cyclobutane after a total of (1.008x10^3) s? Express your answer to three significant figures. Just enter the number (e.g. 2.48x10^-4) and the unit.arrow_forwardPotentially Useful Reference Information -Ea J R = 8.314 k = A· e RT mol·K Calculate the rate constant (k) for a reaction where a 0.1 M first order reactant and a 0.3 M second order reactant result in a rate of 4.5 x 103 M/sec. Report your answer with one significant figure; you do not need to include any units, just the value of k. The molarities given are the initial concentrations for each reactant.arrow_forwardUnder certain conditions the rate of this reaction is zero order in dinitrogen monoxide with a rate constant of 0.0022 Ms: 2N,0 (g) - 2N, (g) +0, (g) Suppose a 400. mL flask is charged under these conditions with 500. mmol of dinitrogen monoxide. After how much time is there only 250. mmol left? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits. 10 Ararrow_forward
- For the gas phase decomposition of isobutyl bromide, (CH3),CHCH,Br–→{CH3),C=CH, + HBr the rate constant at 639 K is 6.60×105 /s and the rate constant at 682 K is 8.07x104 /s. The activation energy for the gas phase decomposition of isobutyl bromide is kJ.arrow_forwardChlorine oxide (CIO), which plays an important role in the depletion of ozone, decays rapidly according to the equation 2CIO(g) →→→ Cl₂(g) + O₂(g) - From the following data, determine the reaction order and calculate the rate constant of the reaction. Time (s) [CIO] (M) 2.91 x 103 8.11 × 10-6 3.64 x 10-3 5.77 × 10-6 4.37x103 4.48 x 10-6 5.10 x 10 3 3.66 x 10-6 5.83 x 10-3 3.09 x 10-6 Reaction order: O O 1 2 Rate constant: k = x 10 Ms (Enter your answer in scientific notation.)arrow_forwardThe decomposition of N,O5 to NO, and O, is first order, with a rate constant of 4.80 x 1o4/s at 45°C. If the initial concentration of N,O5 is 4.18×102 mol/L, what is the concentration of N205 after 548 s? How long would it take for the concentration ofN,O5 to decrease to 1.00 x 10-2 mol/L from an initial concentration of 4.18x102 mol/L?arrow_forward
- Enter your answer in the provided box. The rate constant of a first-order reaction is 3.4 x 10s at 350.°C. If the activation energy is 143 kJ/mol, calculate the temperature at which its rate constant is 7.25 x 10s. PCarrow_forwardUnder certain conditions the rate of this reaction is zero order in hydrogen iodide with a rate constant of 0.0092 M-s : 2 HI (g) - H, (g) +L, (g) Suppose a 450. mL flask is charged under these conditions with 150. mmol of hydrogen iodide. After how much time is there only 75.0 mmol left? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits. dlo x10 8. 미arrow_forwardUnder certain conditions the rate of this reaction zero order in dinitrogen monoxide with a rate constant of 0.0064 M · s: 2N,0 (g) – 2N, (g) +0, (g) Suppose a 3.0 L flask is charged under these conditions with 400. mmol of dinitrogen monoxide. How much is left 5.0 s later? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.arrow_forward
- 13.102 Chlorine oxide (CIO), which plays an important role in the depletion of ozone (see Problem 13.101), decays rapidly at room temperature according to the equation 2C10(g) Cl₂(g) + O₂(g) From the following data, determine the reaction order and calculate the rate constant of the reaction. Time (s) 0.12 x 10-³ 0.96 x 10-³ 2.24 x 10-³ 3.20 x 10-³ 4.00 x 10-³ [CIO] (M) 8.49 x 10-6 7.10 x 10-6 5.79 x 10-6 5.20 x 10-6 4.77 x 10-6arrow_forwardThe first-order rate constant for the decomposition of N2O5, 2N2O5 (g)→4NO2(g) + O2 (g) Part A at 70° C is 6.82 × 10¬3 s. Suppose we start with 2.60x10-2 mol of N2O5 (g) in a volume of 2.5 L. How many moles of N2O5 will remain after 4.0 min ? Express the amount in moles to two significant digits.arrow_forwardUnder certain conditions the rate of this reaction is zero order in hydrogen iodide with a rate constant of 0.0022 M⚫s 1: 2 HI (g) →H₂ (g) +12(g) Suppose a 4.0 L flask is charged under these conditions with 250. mmol of hydrogen iodide. How much is left 7.0 s later? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. X x10arrow_forward
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