b) Given the following symmetry related linear combinations (SALC's) of the 2p-orbitals on the Cl atoms illustrated below, determine their characters to the symmetry operations of D₂ and their overall symmetry. Use extra pages as necessary. y y FB Pd-FA A For the upper left SALC: E D2h- 1 UpLft | t For the upper right SALC: Dab I UpRt I E B 8 C(z) C₂(y) C₂(x) i 4 4 4 FB Pd-FAX (z-axis is also directed toward you) C(z) C₂(y) C₂(x) i -1 1 B o(xy) o(xz) (yz) o(xy) o(xz) o(yz)

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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13+
M-D
-A
y
A
b) Given the following symmetry related linear combinations (SALC's) of the 2p-orbitals
on the Cl atoms illustrated below, determine their characters to the symmetry
operations of D2h and their overall symmetry. Use extra pages as necessary.
y
FB Pd FA-
B
For the upper left SALC:
D₂h
UpLft |
E
M
X
E
B
For the upper right SALC:
D2h-
UpRt I
B
C₂(z) C₂(y) C₂(x) i
1 41
RNITINE
FB-Pd-FAX
C₂(z) C₂(y) C₂(x) i
-1 1 -1 41
TER
(z-axis is also directed toward you)
B
o(xy) o(xz) o(yz)
A
o(xy) o(xz) (yz)
Transcribed Image Text:13+ M-D -A y A b) Given the following symmetry related linear combinations (SALC's) of the 2p-orbitals on the Cl atoms illustrated below, determine their characters to the symmetry operations of D2h and their overall symmetry. Use extra pages as necessary. y FB Pd FA- B For the upper left SALC: D₂h UpLft | E M X E B For the upper right SALC: D2h- UpRt I B C₂(z) C₂(y) C₂(x) i 1 41 RNITINE FB-Pd-FAX C₂(z) C₂(y) C₂(x) i -1 1 -1 41 TER (z-axis is also directed toward you) B o(xy) o(xz) o(yz) A o(xy) o(xz) (yz)
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