At very low temperatures the molar heat capacity of rock salt varies with temperature according to Debye's T³ law: C = kT where k = 1940 J/(mol K) and 0 = 281 K. (a) How much heat is required to raise the temperature of 1.50 mol of rock salt from 13.0 K to 36.0 K? (Hint: Use the change in thermal energy in the form dQ = nCdT and integrate.) (b) What is the average molar heat capacity in this range? (c) What is the true molar heat capacity at 36.0 K?

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At very low temperatures the molar heat capacity of rock salt varies with temperature
according to Debye's T³ law:
C = kT
03
where k = 1940 J/(mol K) and 0 = 281 K.
(a) How much heat is required to raise the temperature of 1.50 mol of rock salt from 13.0
K to 36.0 K? (Hint: Use the change in thermal energy in the form dQ = nCdT and
integrate.)
(b) What is the average molar heat capacity in this range?
(c) What is the true molar heat capacity at 36.0 K?
Transcribed Image Text:At very low temperatures the molar heat capacity of rock salt varies with temperature according to Debye's T³ law: C = kT 03 where k = 1940 J/(mol K) and 0 = 281 K. (a) How much heat is required to raise the temperature of 1.50 mol of rock salt from 13.0 K to 36.0 K? (Hint: Use the change in thermal energy in the form dQ = nCdT and integrate.) (b) What is the average molar heat capacity in this range? (c) What is the true molar heat capacity at 36.0 K?
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