Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Consider the following chemical equation: Overall Reaction: A B2 + BC - AB + C + B2 The proposed mechanism is as follows: BC – B+ C (slow) A B2 + B = AB+ B2 (fast) What is the rate law? Rate = k[B C] O Rate = k[A B,][B] Rate = k[C] O Rate = k[B][C] Rate k[A B2][B C) Rate = k[A B][B,] Rate = k(A B2]arrow_forwardUsing a rate law The rate of a certain reaction is given by the following rate law: rate=k| H, = k[H2]² [NH3] Use this information to answer the questions below. What is the reaction order in H2? What is the reaction order in NH3? What is overall reaction order? At a certain concentration of H2 and NH3, the initial rate of reaction is 7.0 x 105 M/s. What would the initial rate of the reaction be if the concentration of H2 were doubled? Round your answer to 2 significant digits. The rate of the reaction is measured to be 0.120 M / s when = 1.4 M and [NH3] [H2] = 0.79 M. Calculate the value of the rate constant. Round your answer to 2 significant digits. M 0% -2 -1 k = [] M MS S x10 كarrow_forwardFor the reaction:A(g) + B(g) →AB(g) the rate is 0.30 mol/L.s, when [A]0 = [B]0 = 1.0 mol/L. If the reaction is first order in B and second order in A, what is the rate when [A]0 = 1.9 mol/L and [B]0 = 4.3 mol/L?arrow_forward
- The rate of a certain reaction is given by the following rate law: rate = k[NO] [0,] Use this information to answer the questions below. What is the reaction order in NO? What is the reaction order in 02? What is overall reaction order? At a certain concentration of NO and O2, the initial rate of reaction is 0.270 M / s. What would the initial rate of the M reaction be if the concentration of NO were halved? Round S your answer to 3 significant digits. the reaction is measure — 0.60 М and [O-] The rate to be 62.0 M / s when - 1 - 2 k = ||M [NO] 1.2 M. Calculate the value of the •S rate constant. Round your answer to 2 significant digits.arrow_forwardDinitrogen pentoxide, N205, decomposes by a first order reaction with an activation energy of 110 kJ/mol. At 65 °C, the rate constant is k = 5.2 x 10-3 s-1. What is the initial rate of reaction when 8.01 g of N,O5 is confined in a 0.75 liter container and heated to 65 °C? A. 3.98 x 10-4 M/s B. 5.14 x 10-4 M/s C. 0.56 x 10-5 M/s D. 2.31 x 10-2 M/sarrow_forwardConsider the reaction and its rate law. 4A + 3B What is the order with respect to A? order: products What is the order with respect to B? order: What is the overall reaction order? overall order: rate = k[A]²[B]²arrow_forward
- It was found that for the reaction 2 A + B → 3 C the rate law is Rate = k[A][B] · %3D At the initial concentrations [A]o = 0.100 M and [B]o = 0.200 M the initial rate is 0.0500 M/s. %3D What would be the initial rate if the initial concentrations were [A]o = 0.500 M and [B]o = 0.0750 M? 0.0352 M/s 0.0937 M/s O 0.0711 M/s 0.00533 M/s O 0.469 M/sarrow_forwardQuestion is attached.arrow_forwardThe exponents in a rate law describe the effects of the reactant concentrations on the reaction rate and define the reaction order. Consider a reaction for which the rate law is: rate = k[A]m[B]n If m is 1, the reaction is first order with respect to A. If the exponent is 2, the reaction is second order with respect to A. If n is 1, the reaction is first order in B. If m or n is zero, the reaction is zero order in A or B. If m = 1 and n = 1, the overall order of the reaction is second. (m + n = 1 + 1 = 2). 1. What is the difference between a reaction rate and a reaction's rate constant? 2. What does it mean if a reaction is zero order with respect to a reactant? 3. Doubling the concentration of a reactant increases the rate of a reaction four times. What is the order of the reaction with respect to that reactant? 4. Doubling the concentration of a reactant increases the rate of a reaction four times. Tripling the concentration of a different reactant increases the rate of a reaction…arrow_forward
- Would this be zero order ?arrow_forwardThe rate of a certain reaction is given by the following rate law: =k[N₂]²[H₂]² Use this information to answer the questions below. rate What is the reaction order in N₂? What is the reaction order in H₂? What is overall reaction order? At a certain concentration of N₂ and H₂, the initial rate of reaction is 71.0 M/s. What would the initial rate of the reaction be if the concentration of N₂ were halved? Be sure your answer has the correct number of significant digits. The rate of the reaction is measured to be 0.930 M/s when [N₂] = 0.79 M and [H₂] = 0.88 M. Calculate the value of the rate constant. Be sure your answer has the correct number of significant digits. M 04/1 S -3 1 k = M ²³.5²¹ Sarrow_forwardConsider the rate law: Rate = k[NO][O,] Which of the following statements is FALSE regarding this rate law? O The value of k will increase with temperature. O The reaction is 2nd order overall. O The reaction is 1st order with respect to O2 The reaction is 2nd order with respect to NO.arrow_forward
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