are &c. = = 5-18. Molar absorptivity data for the cobalt and nickel complexes with 2,3-quinoxalinedithiol 36,400 and &Ni = 5520 at 510 nm and &c. = 1240 and EN 17,500 at 656 nm. A 0.425-g sample was dissolved and diluted to 50.0 mL. A 25.0-mL aliquot was treated to eliminate interferences; after addition of 2,3-quinoxalinedithiol, the volume was adjusted to 50.0 mL. This solution had an absorbance of 0.446 at 510 nm and 0.326 at 656 nm in a 1.00-cm cell. Cal- culate the concentration in parts per million of cobalt and nickel in the sample. 26

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26-18. Molar absorptivity data for the cobalt and nickel
complexes with 2,3-quinoxalinedithiol are &c.
36,400 and EN₁ = 5520 at 510 nm and Eco = 1240
and EN 17,500 at 656 nm. A 0.425-g sample was
dissolved and diluted to 50.0 mL. A 25.0-mL aliquot
was treated to eliminate interferences; after addition
of 2,3-quinoxalinedithiol, the volume was adjusted to
50.0 mL. This solution had an absorbance of 0.446 at
510 nm and 0.326 at 656 nm in a 1.00-cm cell. Cal-
culate the concentration in parts per million of cobalt
and nickel in the sample.
=
26-
Transcribed Image Text:26-18. Molar absorptivity data for the cobalt and nickel complexes with 2,3-quinoxalinedithiol are &c. 36,400 and EN₁ = 5520 at 510 nm and Eco = 1240 and EN 17,500 at 656 nm. A 0.425-g sample was dissolved and diluted to 50.0 mL. A 25.0-mL aliquot was treated to eliminate interferences; after addition of 2,3-quinoxalinedithiol, the volume was adjusted to 50.0 mL. This solution had an absorbance of 0.446 at 510 nm and 0.326 at 656 nm in a 1.00-cm cell. Cal- culate the concentration in parts per million of cobalt and nickel in the sample. = 26-
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