Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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An unknown compound produces an 1H NMR
spectrum with only three signals: 1.8, 2.8, 7.5
(broad) ppm, all singlets that integrate in a 6:3:1
ratio, respectively. The 13C NMR spectrum shows
4 signals. Both spectra are provided below. The
mass spectrum shows a molecular ion region with
the following peaks: m/z 135 (100%), 136 (5.9%),
137 (33%). Determine the number of carbons,
molecular formula, and propose a structure. Assign
all 1H and 13C NMR signals to specific chemical
environments or specific hydrogens in your
structure.
'H NMR Spectrum of Unknown
8
6
PPM
13C NMR Spectrum of Unknown
160
140
80
60
100
PPM
180
120
40
20
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Transcribed Image Text:An unknown compound produces an 1H NMR spectrum with only three signals: 1.8, 2.8, 7.5 (broad) ppm, all singlets that integrate in a 6:3:1 ratio, respectively. The 13C NMR spectrum shows 4 signals. Both spectra are provided below. The mass spectrum shows a molecular ion region with the following peaks: m/z 135 (100%), 136 (5.9%), 137 (33%). Determine the number of carbons, molecular formula, and propose a structure. Assign all 1H and 13C NMR signals to specific chemical environments or specific hydrogens in your structure. 'H NMR Spectrum of Unknown 8 6 PPM 13C NMR Spectrum of Unknown 160 140 80 60 100 PPM 180 120 40 20
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