
An experiment is conducted in which a quantity of H2(g) is chemically generated in a closed headspace of volume V1 at absolute temperature T1, thereby raising the total pressure from Pa (the initial air pressure) to Pf (the total final pressure of H2(g) + air).
Compose an algebraic expression for the volume (V2) that this sample of H2(g) would occupy if it were isolated (pure -- i.e. no air) at absolute temperature T2 and partial pressure P2.
Note that your expression may contain no other variables than those given above, namely: V1, T1, T2, Pa, Pf, and P2.
V2 =
Now, suppose that the above experiment generated n mol of H2(g), that T2 = 0 °C and that P2 = 1 atm. Give the simple algebraic expression, in terms of V2 and n, which equates to the molar volume of H2(g) at STP.
VM =
8.829×10-4 mol of B2H6(g) (diborane gas) is generated into a 176.0 mL headspace, at 25.0 °C, thus increasing the pressure by 0.1209 atm. If we assume that the diborane gas obeys Boyle's Law and Charle's Law, what would be the expected molar volume at STP?
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