Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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An experiment is conducted in which a quantity of H2(g) is chemically generated in a closed headspace of volume V1 at absolute temperature T1, thereby raising the total pressure from Pa (the initial air pressure) to Pf (the total final pressure of H2(g) + air).
Compose an algebraic expression for the volume (V2) that this sample of H2(g) would occupy if it were isolated (pure -- i.e. no air) at absolute temperature T2 and partial pressure P2.
Note that your expression may contain no other variables than those given above, namely: V1T1T2PaPf, and P2.

V2 =

Now, suppose that the above experiment generated n mol of H2(g), that T2 = 0 °C and that P2 = 1 atm. Give the simple algebraic expression, in terms of V2 and n, which equates to the molar volume of H2(g) at STP.

VM =

8.829×10-4 mol of B2H6(g) (diborane gas) is generated into a 176.0 mL headspace, at 25.0 °C, thus increasing the pressure by 0.1209 atm. If we assume that the diborane gas obeys Boyle's Law and Charle's Law, what would be the expected molar volume at STP?

Give answer to 4 significant figures

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