Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- Q46arrow_forwardREACTION ENGINEERING Consider a heterogeneous gas-phase catalytic reaction:AB(g)→A(g)+B(g) (Catalyst) The surface reaction mechanism follows three steps: AB(g) +S <----> AB*S (Adsorption)AB*S<----> B*S+A(g) (Surface reaction)B*S <---> B(g) + S (Desorption) (a) Derive the rate law assuming (1) surface reaction is rate limiting, and (2) desorption is rate-limiting. Express the overall reaction rate (- Tan) in terms of total number of sites on the surface, C. partial pressures of the gas species (ie., Pab Pa and Pb), rate constants of adsorption, the surface reaction, and desorption (ka,ks, and kd), and the equilibrium constants of adsorption, the surface reaction, and desorption (ie., Ka. Ks and Kd).arrow_forwardF2 gas and excess iodine solid are heated together at high temperatures. The iodine sublimes and gaseous iodine heptafluoride forms. A 2.50L reaction vessel contains 350 torr of F2 gas and 2.50g of solid iodine at 250K which is then heated to 550K. What is the number of moles of excess iodine that would be left over once all the fluorine is used up? What is the total pressure at the end of the reaction? What is the partial pressure of the left over iodine gas as the end of the reaction? What is the balanced chemical equation for this reaction?arrow_forward
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- Solve correctly please.arrow_forward1. A house needs 200,000 Btu per day so that its temperature remanins at 68oF. How much CaCl26H2O(s) needs to be used to save enough energy for one day use? The process contains the heating of CaCl26H2O(s) from 68oF to 86oF and the reaction CaCl26H2O(s) = CaCl22H2O(s) + 4H2O(g). The water from the dehydration evaporates during the process. CaCl26H2O(s): ΔHof=-2607.89kJ/gmol, Cp=1.34J/g(oC) CaCl22H2O(s): ΔHof=-1402.90kJ/gmol, Cp=0.97J/g(oC)arrow_forwardREACTION ENGINEERING Consider a heterogeneous gas-phase catalytic reaction:AB(g)→A(g)+B(g) (Catalyst) The surface reaction mechanism follows three steps: AB(g) +S <----> AB*S (Adsorption)AB*S<----> B*S+A(g) (Surface reaction)B*S <---> B(g) + S (Desorption) a) Derive the initial rates (AR) of the reaction, assuming there is no product (ie., A and B) in the feed (ie., PA Pao=0), assuming adsorption is the rate determining step. Use initial pressure of AB (ie., PARA), total number of sites on the surface (C), and the rate and equilibrium constants in the expressions.Hint: Based on the reaction mechanism, only AB and B are adsorbed on the surface, i.e., there is no evidence that A alone can be adsorbed on the surface.arrow_forward
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