Ammonium dichromate is sometimes known as Vesuvian Fire, because of its use in demonstrations of tabletop "volcanoes". Using the given data, calculate the heat of reaction for the following reaction: (NH4)2Cr207(s) → Cr2O3(s) + N2(g) +4H2O(g) s° ΔΗΡ (k) mol") (U mol- K-') AG (k) mol) Species Nitrogen N;(g) 191.5 N(g) NH,(g) 472.704 153.19 455.579 -46.11 192.3 -16.5 NH,(aq) NH,*(aq) N,H,(() (NH,),AsO,(aq) -80.29 111.3 -26.50 -132.51 113.4 -79.31 50.63 121.2 149.2 -1268 NH,Br(s) -270.83 113 -175.2 NH,CI(s) NH,CI(aq) -314.4 94.6 -201.5 - 300.2

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Ammonium dichromate is sometimes known as
Vesuvian Fire, because of its use in demonstrations
of tabletop "volcanoes". Using the given data,
calculate the heat of reaction for the following
reaction:
(NH4)2Cr207(s) → Cr2O3(s) + N2(g) +4H2O(g)
AH,°
(kJ
mol")
s°
U mol-
K-')
(k)
mol')
Species
Nitrogen
N;(g)
N(g)
NH,(g)
191.5
472.704
153.19
455.579
-46.11
192.3
-16.5
NH,(aq)
NH,*(aq)
-80.29
111.3
-26.50
-132.51
113.4
-79.31
N,H(€)
50.63
121.2
149.2
(NH,);AsO,(aq)
NH,Br(s)
-1268
-270.83
113
-175.2
NH,C(s)
NH,Cl(aq)
NH,HCO,(s)
-314.4
94.6
-201.5
- 300.2
-847
12.1
-666
- 201.4
NH,I(s)
NH,NO,(s)
117
-113
- 365.6
151.1
-184.0
(NH,);SO,(s)
-1180.85
220.1
-901.67
NF,(g)
-125
260.6
-83.3
210.7
86.57
NO(g)
NO:(g)
90.25
33.2
240.0
51.30
N,O(g)
82.05
219.7
104.2
83.72
321.28
139.46
(3)'O°N
304.2
N,O,(g)
9.16
97.82
N;O;(g)
N,O;(s)
11
356
115
-43.1
178
114
Transcribed Image Text:Ammonium dichromate is sometimes known as Vesuvian Fire, because of its use in demonstrations of tabletop "volcanoes". Using the given data, calculate the heat of reaction for the following reaction: (NH4)2Cr207(s) → Cr2O3(s) + N2(g) +4H2O(g) AH,° (kJ mol") s° U mol- K-') (k) mol') Species Nitrogen N;(g) N(g) NH,(g) 191.5 472.704 153.19 455.579 -46.11 192.3 -16.5 NH,(aq) NH,*(aq) -80.29 111.3 -26.50 -132.51 113.4 -79.31 N,H(€) 50.63 121.2 149.2 (NH,);AsO,(aq) NH,Br(s) -1268 -270.83 113 -175.2 NH,C(s) NH,Cl(aq) NH,HCO,(s) -314.4 94.6 -201.5 - 300.2 -847 12.1 -666 - 201.4 NH,I(s) NH,NO,(s) 117 -113 - 365.6 151.1 -184.0 (NH,);SO,(s) -1180.85 220.1 -901.67 NF,(g) -125 260.6 -83.3 210.7 86.57 NO(g) NO:(g) 90.25 33.2 240.0 51.30 N,O(g) 82.05 219.7 104.2 83.72 321.28 139.46 (3)'O°N 304.2 N,O,(g) 9.16 97.82 N;O;(g) N,O;(s) 11 356 115 -43.1 178 114
NO(g)
NO;(g)
90.25
210.7
86.57
33.2
240.0
51.30
N,O(g)
N;O,(g)
82.05
219.7
104.2
83.72
321.28
139.46
(S)*O°N_
(3)*O°N
9.16
304.2
97.82
11
356
115
N,O;(s)
-43.1
178
114
NOCI(g)
HNO,(€)
HNO,(g)
52.59
264
66,36
-174.1
155.6
-80.79
-135.1
266.2
-74.77
HNO, (aq)
-206.6
146
-110.5
Hydrogen
H(g)
218.0
114.6
203.3
H;(g)
130.6
H,O(€)
-285.8
69.91
-237.2
H,O(g)
-241.8
188.7
-228.6
H;O;()
-187.8
109.6
-120.4
Cbromium
Cr(s)
23.8
Cr,O;(s)
Cr,Cl;(s)
-1139.7
81.2
- 1058.1
-556.5
123.0
-486.1
(NH,) ¿Cr,O;(s)
-1807
A
-299.9 kJ/mol
В
3,913.9 kJ/mol
299.9 kJ/mol
D
-3,913.9 kJ/mol
Transcribed Image Text:NO(g) NO;(g) 90.25 210.7 86.57 33.2 240.0 51.30 N,O(g) N;O,(g) 82.05 219.7 104.2 83.72 321.28 139.46 (S)*O°N_ (3)*O°N 9.16 304.2 97.82 11 356 115 N,O;(s) -43.1 178 114 NOCI(g) HNO,(€) HNO,(g) 52.59 264 66,36 -174.1 155.6 -80.79 -135.1 266.2 -74.77 HNO, (aq) -206.6 146 -110.5 Hydrogen H(g) 218.0 114.6 203.3 H;(g) 130.6 H,O(€) -285.8 69.91 -237.2 H,O(g) -241.8 188.7 -228.6 H;O;() -187.8 109.6 -120.4 Cbromium Cr(s) 23.8 Cr,O;(s) Cr,Cl;(s) -1139.7 81.2 - 1058.1 -556.5 123.0 -486.1 (NH,) ¿Cr,O;(s) -1807 A -299.9 kJ/mol В 3,913.9 kJ/mol 299.9 kJ/mol D -3,913.9 kJ/mol
Expert Solution
steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Thermodynamics
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY