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- Determine which reactions would occur (substitution, elimination, both, or neither). CH;CH,OH a. SN1 O b. E1 C. SN1 & E1 O d. SN2 е. Е2 O f. SN2 & E2 g. No reactionDoes the equilibrium favor the reactants or products in each substitution reaction? a. CH;CH2-NH2 Br CH;CH2-Br + "NH2 b. "CN CN + I-4. Syn and anti addition can occur with alkenes. 1. Describe syn and anti addition. b. Give an example of syn addition to an alkene and explain why it is syn. c. Give an example of anti addition to an alkene and explain why it is anti. 5. The following reactions shows the dehydration of 2-methylcyclohexanol. Why is 1-methylcyclohexene the major product? X OH H3PO4 84% 16%
- Draw the organic product(s) formed when CH3CH2CH2OH is treated with each reagent. a.H2SO4 b.NaH c.HCl + ZnCl2 d.HBr e.SOCl2, pyridine f.PBr3 g.TsCl, pyridine h. [1] NaH; [2] CH3CH2Br [1] i.TsCl, pyridine; [2] NaSH j.POCl3, pyridineCH2 H3C H3C COOH Reagents e. PB13 f. NaCN then H3O* g. NBS, CCI4 h. CrO3, H2SO4 а. HBr b. Mg, ether c. CO2, ether then H3O* d. BH3, THF then H2O2, OH"2. Name each alkyne. a. CH3CH₂CH₂C=CH b. CH3CH₂CH₂C=CCH3 3. Predict the product of the following reactions. a. CH = CCH3 + HCI b. CH CCH₂CH3 + O2
- Create product III a. H 1. PhCH2 PPh3/ NaOH 2. H3O+4. What is the product of the following reaction? A. B. OH 1) CH3CH₂CH3MgBr 2) H₂O C. HO D.Draw the products obtained from the SN2 reaction of a. 2-bromobutane and methoxide ion. b. (R)-2-bromobutane and methoxide ion. c. (S)-3-chlorohexane and hydroxide ion. d. 3-iodopentane and hydroxide ion.
- Examine the reactant and product for each reaction. Label each transformation as an addition, elimination, or substitution. Br А. Br ОН elimination addition С. substitution D. B.1. Draw the products in each reaction. a. H b. CH3-C-CH₂CH3 CI -OH K+ -OC(CH3)3 CH₂CH3 a Xa C. d. CH₂CH₂OH CH3CH₂O™a. 2. Draw the product(s) for each reaction d. b. OH a. NaH, DCM b. CH,CH₂Br OH a. PBr3, THF b. MeOH Br a. H₂O b. NaH, THF OH H₂SO4 Δ