Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Which molecule will have a higher boiling point and why

a.

 

molecule ‘b’ will have a higher boiling point as the molecule is more compact and therefore will pack better.


 

b.

molecule ‘b’ will have the higher boiling point as the methyl groups are tetrahedrally arranged around the central carbon, giving it higher symmetry.

c.
molecule ‘a’ will have a higher boiling point as it has a greater surface for London dispersion forces.
d.

molecule ‘a’ will have a higher boiling point as it has a higher molecular weight than molecule ‘b’.

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