1. a) What is the meaning of labil and inert complexes? For the following complexes, orderthem according to their increasing lability, and explain your reasoning in detail.- [CFFG]* , [Fe(CO)c]²* , [Cr(OH)6J³* , [Mn(H2O)c]³*b) Show the molecular orbital energy level diagram for the [Fe(CN)«J+ complexconsidering o and a interaction of the orbitals (Symmetry Adapted Orbitals for Oh: s=a1g,px=tiu, P;=tiu, ptiu, d=eg, d=eg, dxy=t25, dr=t25, dyz-2g).c) Both [Fe(CN)6]+ and [Fe(CN)k]* might be toxic because of the possibility ofdissociation of the complexes to give cyanide (CN) ion. Decide which one will be morepoisonous by taking into account Fe-C bond strengths in these complexes.

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a) What is the meaning of labil and inert complexes? For the following complexes, order them according to their increasing lability, and explain your reasoning in detail. - [CTFG]+ , [Fe(CO)cJ²* , [Cr(OH)cJ* , [Mn(H2O)c]²*

a) What is the meaning of labil and inert complexes? For the following complexes, order them according to their increasing lability, and explain your reasoning in detail. - [CTFG]+ , [Fe(CO)cJ²* , [Cr(OH)cJ* , [Mn(H2O)c]²*

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

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Coordination Chemistry

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Question

1. a) What is the meaning of labil and inert complexes? For the following complexes, order
them according to their increasing lability, and explain your reasoning in detail.
- [CFFG]* , [Fe(CO)c]²* , [Cr(OH)6J³* , [Mn(H2O)c]³*
b) Show the molecular orbital energy level diagram for the [Fe(CN)«J+ complex
considering o and a interaction of the orbitals (Symmetry Adapted Orbitals for Oh: s=a1g,
px=tiu, P;=tiu, ptiu, d=eg, d=eg, dxy=t25, dr=t25, dyz-2g).
c) Both [Fe(CN)6]+ and [Fe(CN)k]* might be toxic because of the possibility of
dissociation of the complexes to give cyanide (CN) ion. Decide which one will be more
poisonous by taking into account Fe-C bond strengths in these complexes.

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