Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Consider an electrochemical cell made up of Au Au* and Co²+ | Co³+ half-cells. Part 1 of 2 Write the equation for the cell reaction that occurs under standard-state conditions. Be sure to include the physical state of each species in the reaction. Part 2 of 2 E = ローロ V 00 Calculate the standard emf of a cell that uses the Au Au and Co²+ | Co³+ half-cell reaction at 25 °C. Round your answer to 2 significant digits. Note: Reference the Standard reduction potentials at 25 °C table for additional information. 09 Sarrow_forwardA voltaic electrochemical cell is constructed using the following reaction. The half-cell components are separated by a salt bridge. Br2(1) + Mn(s) 2Br"(aq) + Mn2+(aq) Write the reactions that take place at the anode and at the cathode, the direction in which the electrons migrate in the external circuit, and the direction the anions in the salt bridge migrate. Use smallest possible integer coefficients. If a box is not needed, leave it blank. Enter the reaction that takes place at the anode. Include state symbols: Enter the reaction that takes place at the cathode. Include state symbols: In the external circuit, electrons migrate the Mn electrode the Br2 electrode. Anions migrate the salt bridge the Br2 compartment.arrow_forwardMnO4– + Sn ----> MnO2 + Sn2+ A) Identify the half-reaction that occurs at the cathode. B) Identify the oxidizing agent and anode. C) standard cell potential? D) What will be the potential of a cell constructed using 57.0 g MnO2, 1.57 M MnO4–, 14.8 g Pt, 12.5 g Sn and 0.87 M Sn2+ at pH 2.5?arrow_forward
- Consider the following voltaic cellat 25°C: Al(s) | Al3*(0.20 M, aq) || Al3+(0.75 M, aq) | Al(s) If the standard reduction potential for the Al3+(aq) /Al(s) redox couple is -1.66 V, what is the overall cell reaction and the cell potential of the voltaic cell shown above? (Reference the cell as written above.) The overall cell reaction is Al3+(0.75 M, aq) AIS*(0.20 M, ag) and E°cell = +0.0113 V. There is no overall cell reaction and E°cell = 0.00 V. The overall cell reaction is Al3+(0.20 M, aq) Als*(0.75 M, aq) and E°cell = +0.0113 V. The overall cell reaction is Al3+(0.20 M, aq) →A13+(0.75 M, ag) and E°cell| = -0.0113 V. The overall cell reaction is Al3*(0.75 M, aq) →AI3*(0.20 M, aq) and E°cell = -0.0113 V. None of thesearrow_forwardConsider the following half-reactions and their standard reduction potentials then give the standard line (cell) notation for a voltaic cell built on these half reactions. Mn2*(aq) + 2 e Mn(s) E° = -1.18 V Fe(aq) +3 e Fe(s) E° = -0.036 V A. Fe(s) | Fe3t(aq, 1.0 M) || Mn (s) | Mn 2*(aq. 1.0 M) B. Mn (s) | Mn 2*(aq, 1.0 M) | | Fe(s) | Fe(aq. 1.0 M) C. Fe(s) | Fe3t(aq. 1.0 M) || Mn2*(aq, 1.0 M) | Mn(s) D. Mn (s) | Mn 2*(aq. 1.0 M) || Fe(aq, 1.0 M) | Fe(s)arrow_forwardA voltaic cell is constructed in which the anode is a Sn|Sn²+ half cell and the cathode is a Cu+| Cu²+ half cell. The half-cell compartments are connected by a salt bridge. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) I The anode reaction is: + The cathode reaction is: + The net cell reaction is: + In the external circuit, electrons migrate electrode the Cu+I Cu²+ electrode. In the salt bridge, anions migrate the Sn|Sn²+ compartment. + + + the Sn|Sn²+ the Cu+I Cu2+ compartmentarrow_forward
- Consider the voltaic cellZn(s) | Zn2+(aq, 0.100 mol L−1) || Cu2+(aq, 1.200 mol L−1) | Cu(s)with the concentrations in the compartments as indicated. The circuit is closed and the battery is discharged until the concentration of Cu2+(aq) is 0.850 mol L−1. What is the electromotive force of the cell at that stage in the discharge?A) 1.048 VB) 0.508 VC) 0.434 VD) 1.132 VE) 1.108 Varrow_forwardA voltaic cell is constructed in which the following cell reaction occurs. The half-cell compartments are connected by a salt bridge. Pb2+(aq) + Mn(s) Pb(s) + Mn2+(aq) The anode reaction is: The cathode reaction is: + + In the external circuit, electrons migrate e the Mn|Mn2+ electrode e the Pb|Pb2+ electrode. In the salt bridge, anions migrate e the Pb|Pb²+ compartment e the Mn|Mn2+ compartment. +arrow_forwardThe cell potential of the following cell at 25°C is 0.475 V: Zn|Zn?t (1.0 M) || H* (test solution) H2 (1.0 atm)|Pt What is the pH of the test solution? The standard reduction potential for Zn+ is –0.76 V. (Enter your answer to two significant figures.) pH =arrow_forward
- Enter electrons as e A voltaic cell is constructed in which the anode is a Fe2+|Fe3+ half cell and the cathode is a F|F, half cell. The half-cell compartments are connected by a salt bridge. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) The anode reaction is: The cathode reaction is: The net cell reaction is: +. In the external circuit, electrons migrate the Fe2+|Fe3+ electrode the F|F, electrode. from to In the salt bridge, anions migrate the F|F, compartment 3- the Fe2+|Fe+ compartment. +. +. 1arrow_forwardBalance the REDOX reaction associated with the cell shown below, in acidic medium: 2+ Fe(s) | Fe² || MnO (aq) Mn²) | Pt(s) Μη '(aq) 4(aq)' Enter the number for the coefficient of H₂O in the balanced equation:arrow_forward3) Draw a picture of the galvanic cell represented by the line notation below and then write the reduction half-reactions for each electrode. Also identify the anode and cathode for each half cell. Pt (s) | Fe3+ (aq), Fe2+ (aq) || Cr2O72-(aq), Cr3+ (aq), HA (aq) | Pt (s)arrow_forward
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