
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
![A voltaic cell consists of Cu?*/Cu and Cd²*/Cd half-cells. Each
compartment has a volume of 0.500 L with the following initial
concentrations: [Cu2*] = 1.250 M; [Cd2*] = 0.250 M at 25°C. What is
the [Cu2*] when the voltage has dropped to 0.727 V? (E° for Cu²*/Cu
= 0.340 V and Eº for Cd2*/Cd = -0.400 V.)
%D
%3D](https://content.bartleby.com/qna-images/question/24f7b1c8-8e35-4ae9-b134-2d55bff519a6/53187800-ffc2-4276-adc7-6ca001caddaa/kffver_thumbnail.png)
Transcribed Image Text:A voltaic cell consists of Cu?*/Cu and Cd²*/Cd half-cells. Each
compartment has a volume of 0.500 L with the following initial
concentrations: [Cu2*] = 1.250 M; [Cd2*] = 0.250 M at 25°C. What is
the [Cu2*] when the voltage has dropped to 0.727 V? (E° for Cu²*/Cu
= 0.340 V and Eº for Cd2*/Cd = -0.400 V.)
%D
%3D
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution
Trending nowThis is a popular solution!
Step by stepSolved in 2 steps

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Consider the galvanic cell based on the following half-reactions. Ag+ + e → Ag Cd²+ + 2e →→ Cd (a) Determine the overall cell reaction and calculate º chemPad XX² cell 8° = +0.80 V 8⁰ = -0.40 V V AGO K Help Greek (b) Calculate AGº (in kJ) and K for the cell reaction at 25°C. kJ (in V). (Use the lowest possible whole number coefficients. Omit states-of-matter from your answer.) cell (c) Calculate cell (in V) at 25°C when [Ag+ ] = V 1.0×10-4 M and [Cd²+] = 1.0×10-² M.arrow_forwardConsider a galvanic cell with the anode containing a Zn metal electrode and a 0.10M Zn(NO3)2 solution and the other half-cell containing a Sn metal electrode and a 0.10M Sn(NO3)2 solution. If the measured Ecell value is +650mV and the Zn2+/Zn reduction potential is assumed to be -790mV, what is the Sn2+/Sn reduction potential?arrow_forwardA voltaic cell using Pb²⁺/Pb and Ni²⁺/Ni half-cells is set up at standard conditions, and each compartment has a volume of 355 mL. What is the cell potential, in V, after it has delivered 0.150 A for 51.0 hours at 25 °C? (E° for Pb²⁺/Pb = -0.130 V and E° for Ni²⁺/Ni = -0.250 V.)arrow_forward
- Consider the following voltaic cellat 25°C: Al(s) | Al3*(0.20 M, aq) || Al3+(0.75 M, aq) | Al(s) If the standard reduction potential for the Al3+(aq) /Al(s) redox couple is -1.66 V, what is the overall cell reaction and the cell potential of the voltaic cell shown above? (Reference the cell as written above.) The overall cell reaction is Al3+(0.75 M, aq) AIS*(0.20 M, ag) and E°cell = +0.0113 V. There is no overall cell reaction and E°cell = 0.00 V. The overall cell reaction is Al3+(0.20 M, aq) Als*(0.75 M, aq) and E°cell = +0.0113 V. The overall cell reaction is Al3+(0.20 M, aq) →A13+(0.75 M, ag) and E°cell| = -0.0113 V. The overall cell reaction is Al3*(0.75 M, aq) →AI3*(0.20 M, aq) and E°cell = -0.0113 V. None of thesearrow_forwardA voltaic cell consists of an Al/Al3+ half-cell and a Fe2+/Fe3+ half-cell. The standard reduction potential for Al3+ is −1.66V and for Fe3+ is 0.77 V. Calculate Ecell at 25 ºC when the concentration of [Al3+] = 9.51 x 10-4 M , [Fe3+]= 6.24 x 10-3 M, and [Fe2+]= 5.74 x 10-5 Marrow_forwardA voltaic cell is constructed in which the anode is a Sn|Sn²+ half cell and the cathode is a Cu+| Cu²+ half cell. The half-cell compartments are connected by a salt bridge. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) I The anode reaction is: + The cathode reaction is: + The net cell reaction is: + In the external circuit, electrons migrate electrode the Cu+I Cu²+ electrode. In the salt bridge, anions migrate the Sn|Sn²+ compartment. + + + the Sn|Sn²+ the Cu+I Cu2+ compartmentarrow_forward
- A voltaic cell is constructed in which the following cell reaction occurs. The half-cell compartments are connected by a salt bridge. Pb2+(aq) + Mn(s) Pb(s) + Mn2+(aq) The anode reaction is: The cathode reaction is: + + In the external circuit, electrons migrate e the Mn|Mn2+ electrode e the Pb|Pb2+ electrode. In the salt bridge, anions migrate e the Pb|Pb²+ compartment e the Mn|Mn2+ compartment. +arrow_forward5. What is voltage of the following cell? Sn(s) | Sn(NO3)2 (0.100 M) || AgNO3(0.020 M) | Ag(s)arrow_forwardA voltaic cell using Pb²⁺/Pb and Ni²⁺/Ni half-cells is set up at standard conditions, and each compartment has a volume of 355 mL. What is the cell potential, in V, after it has delivered 0.150 A for 51.0 hours at 25.0 °C? (E° for Pb²⁺/Pb = -0.130 V and E° for Ni²⁺/Ni = -0.250 V.)arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning

Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY