A titration of 50.0 mL of 0.10 M Sn2+ with 0.2 M Fe3+ in 1 M HCl to give Fe2+ and Sn4+ using Pt and calomel electrodes. Assuming the standard potential for Sn2+/Sn4+ = 0.139V ; calomel, 0.241 V; Fe2+/Fe3+ = 0.732 V. This my cathode reaction: Fe3+ (aq)  + 1 electron <-> Fe2+(s) and anode reaction: Sn2+(s) <-> Sn4+(aq) + 2 electrons. How will I write my Nernst equation for the cell voltage for the oxidation reaction?

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter23: Potentiometry
Section: Chapter Questions
Problem 23.23QAP: The following cell was found to have a potential of —0.492 V: Ag|AgCl(sat’d)||HA(0.200 M),NaA(0.300...
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A titration of 50.0 mL of 0.10 M Sn2+ with 0.2 M Fe3+ in 1 M HCl to give Fe2+ and Sn4+ using Pt and calomel electrodes. Assuming the standard potential for Sn2+/Sn4+ = 0.139V ; calomel, 0.241 V; Fe2+/Fe3+ = 0.732 V.

This my cathode reaction: Fe3+ (aq)  + 1 electron <-> Fe2+(s) and anode reaction: Sn2+(s) <-> Sn4+(aq) + 2 electrons.

How will I write my Nernst equation for the cell voltage for the oxidation reaction?

 

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