Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Row 3: Your answer is wrong. In addition to checking your math, check that you used the right data and DID NOT round any intermediate calculations.
A student runs two experiments with a constant-volume "bomb" calorimeter containing 1100. g of water (see sketch at
right).
First, a 7.000 g tablet of benzoic acid (CH₂CO₂H) is put into the "bomb" and burned completely in an excess of
oxygen. (Benzoic acid is known to have a heat of combustion of 26.454 kJ/g.) The temperature of the water is observed
to rise from 15.00 °C to 53.26 °C over a time of 12.3 minutes.
Next, 5.420 g of acetylene (C₂H₂) are put into the "bomb" and similarly completely burned in an excess of oxygen.
This time the temperature of the water rises from 15.00 °C to 74.42 °C.
Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below
about this reaction:
Is this reaction exothermic, endothermic, or neither?
If you said the reaction was exothermic or endothermic, calculate the amount of heat that was
released or absorbed by the reaction in the second experiment.
Calculate the reaction enthalpy ΔΗ. rxn per mole of CO₂.
O exothermic
O endothermic
neither
287.6 kJ
2C₂H₂(g) + 50₂(g) → 4CO₂(g) + 2H₂O(g)
Be sure any of your answers that are calculated from measured data are rounded to the correct number of significant digits.
Note for advanced students: it's possible the student did not do these experiments sufficiently carefully, and the values you calculate may not exactly match
published values for this reaction.
-691.3
stirrer
kJ
mol
thermometer
chemical reaction
"bomb"
A "bomb" calorimeter.
x10
water
X
insulation
?
olo
Ar
expand button
Transcribed Image Text:Try Again Row 3: Your answer is wrong. In addition to checking your math, check that you used the right data and DID NOT round any intermediate calculations. A student runs two experiments with a constant-volume "bomb" calorimeter containing 1100. g of water (see sketch at right). First, a 7.000 g tablet of benzoic acid (CH₂CO₂H) is put into the "bomb" and burned completely in an excess of oxygen. (Benzoic acid is known to have a heat of combustion of 26.454 kJ/g.) The temperature of the water is observed to rise from 15.00 °C to 53.26 °C over a time of 12.3 minutes. Next, 5.420 g of acetylene (C₂H₂) are put into the "bomb" and similarly completely burned in an excess of oxygen. This time the temperature of the water rises from 15.00 °C to 74.42 °C. Use this information, and any other information you need from the ALEKS Data resource, to answer the questions below about this reaction: Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in the second experiment. Calculate the reaction enthalpy ΔΗ. rxn per mole of CO₂. O exothermic O endothermic neither 287.6 kJ 2C₂H₂(g) + 50₂(g) → 4CO₂(g) + 2H₂O(g) Be sure any of your answers that are calculated from measured data are rounded to the correct number of significant digits. Note for advanced students: it's possible the student did not do these experiments sufficiently carefully, and the values you calculate may not exactly match published values for this reaction. -691.3 stirrer kJ mol thermometer chemical reaction "bomb" A "bomb" calorimeter. x10 water X insulation ? olo Ar
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