Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- 200.0 mL of 0.200 M HNO3 is added to 200.0 mL of 0.200 M KOH in a coffee cup calorimeter. The neutralization reaction that occurs can be described by the chemical equation- HNO3(aq) + KOH(aq) → KNO3(aq) + H₂O(l) Before the solutions are mixed they are both at 23.00 °C. After the mixing of the solutions the temperature increases until it remains constant at 24.39 °C. Assuming no heat lost to the surroundings, how much heat was lost in this reaction? (Assume the specific heats and densities of the solutions is the same as water.)arrow_forwardWhich of the reactions are exothermic? 2 Mg(s) + O₂(g) - NH3(g) + HCl(g) -> NH₂Cl(s) + heat AgCl(s) + heat. -> Ag+ (aq) + Cl(aq) 2 Fe₂O3(s) + 3 C(s) + heat 4 Fe(s) + 3 CO₂(g) - 2 MgO(s) + heat C(graphite) + O₂(g) → CO₂(g) + heat - - ✓CH₂(g) + 2O₂(g) → CO₂(g) + 2 H₂O(1) + heat -> Incorrectarrow_forward3. The heat of the solution of a solid sample was determined using a coffee cup calorimeter that contains 250ml of water initially at 25C. As the sample is dissolved in the water, the temperature of the water decreased to 11C. What is the heat of the solution of the sample? Assume that the density of water is 1.00g/ml and that the coffee cup is a good insulator. Is the process endothermic or exothermic?arrow_forward
- 6arrow_forwardWhen 145 mL of 0.212 M NaCl(aq) and 145 mL of 0.212 M AgNO3(aq), both at 21.1°C, are mixed in a coffee cup calorimeter, the temperature of the mixture increases to 23.7°C as solid AgCl forms. NaCl(aq) + AgNO3(aq) → AgCl(s) + NaNO3(aq) This precipitation reaction produces 3.14 ✕ 103 J of heat, assuming no heat is absorbed by the calorimeter, no heat is exchanged between the calorimeter and its surroundings, and that the specific heat and density of the solutions are the same as those for water (4.18 J/g·°C, and 0.997 g/mL, respectively). Using this data, calculate ΔH in kJ/mol of AgNO3(aq) for the given reaction.arrow_forwardIn a Calorimetry experiment, a chemical reaction causes the temperature of the solution in the chamber to raise from 20.1 °C to 69.3 °C. Knowing that the solution weights 600. g, and specific heat of the solution is 4.18 J g–1 K–1, the heat released by the reaction is ______ .arrow_forward
- A sample of 27.8 g of ammonium nitrate, NH4NO3, was dissolved in 130.2 g of water in a coffee cup calorimeter. The temperature changed from 28.94 °C to 16.51 °C. Calculate the heat of solution of ammonium nitrate in kJ/mol. Assume that the energy exchange involves only the solution and that the specific heat of the solution is 4.18 J/g°C. Heat of solution = i kJ/molarrow_forwardA student mixes 67.0 mL of a 2.01 M sodium hydroxide solution with 22.4 mL of 6.45 M hydrochloric acid. The temperature of the mixture rises 17.2 ° C. The density of the resulting solution is 1.00 g mL and has a specific heat capacity of 4.184 J g · ° C . The heat capacity of the calorimeter is 16.97 J ° C . Part 1: (a) Identify the limiting reagent for the reaction. Part 2: (b) Calculate the heat of reaction (in J). qrxn = × 10 JEnter your answer in scientific notation. Part 3 out of 3 (c) Find the enthalpy of neutralization (in kJ/mol). ΔHneutralization = ____ kj/molarrow_forwardConsider these reactions: Reaction 1: H₂(g) + Cl₂(g) → 2HCl(g) Reaction 2: 20F₂ (g) → O₂(g) + 2 F₂ (g) Reaction 3: N₂(g) + 2O₂(g) → 2NO₂ (9) Use Reaction 1. AH = -184.6 kJ AH = -49.4 kJ AH = +66.4 kJ Determine the mass, in grams, of chlorine gas consumed (with excess H₂) when 1,861.0 kJ of energy is released from the system. Round to the nearest whole number. Answer:____ garrow_forward
- 11.8 g of a soluble ionic compound is dissolved in 91.6 mL of water in a coffee-cup calorimeter, and the temperature of the solution changes from 24.80°C to 29.14°C. Assume the water has a density of 1.00 g/mL and that the total mass of the solution has the specific heat of water (4.186 J/g.K). Calculate the enthalpy change for the dissolution of this substance in kJ.arrow_forwardConsider these reactions, where M represents a generic metal. 1. 2 M(s) + 6 HCI(aq) → 2 MCl, (aq) + 3 H, (g) AH1 = -698.0 kJ HCl(g) → HCI(aq) AH = -74.8 kJ H, (g) + Cl, (g) → 2 HCl(g) AH3 = -1845.0 kJ MCI, (s) → MCI, (aq) AH = -292.0 kJ Use the given information to determine the enthalpy of the reaction 2 M(s) + 3 Cl, (g) → 2 MCI, (s) 2. 3. 4.arrow_forwardWhen 130. mL of 0.204 M NaCl(aq) and 130. mL of 0.204 M AgNO3(aq), both at 21.1°C, are mixed in a coffee cup calorimeter, the temperature of the mixture increases to 23.6°C as solid AgCl forms. NaCl(aq) + AgNO3(aq) → AgCl(s) + NaNO3(aq) This precipitation reaction produces 2.71x10³ J of heat, assuming no heat is absorbed by the calorimeter, no heat is exchanged between the calorimeter and its surroundings, and that the specific heat and density of the solutions are the same as those for water (4.18 J/g.°C, and 0.997 g/mL, respectively). Using this data, calculate AH in kJ/mol of AgNO3(aq) for the given reaction. 4.0✔✓ kJ/molarrow_forward
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