Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A galvanic cell at a temperature of 25.0 °C is powered by the following redox reaction: 2+ 2 MnO4 (aq) + 16H* (aq) +5Pb (s) → 2Mn² (aq) +8H₂0 (1) +5 Pb²+ (aq) Suppose the cell is prepared with 5.05 M MnO4 and 1.25 M H in one half-cell and 5.98 M Mn² Calculate the cell voltage under these conditions. Round your answer to 3 significant digits. 0 D.O X μ DO 3 and 2.24 M Pb²+ in the other.arrow_forwardA concentration cell consisting of two hydrogen electrodes (P H ₂ = 1atm), where the cathode is a standard hydrogen electrode and the anode solution has an unknown pH, has a cell voltage of 0.201 V. What is the pH in the unknown solution? Assume the temperature of the solutions is 298 K. pH =arrow_forward1)A voltaic cell is constructed, based on the Zn/Sn2+ ion reaction. Zn + Sn2+ → Zn2+ + Sn The standard cell potential is 0.626 V. Temperature is 298 K. What is the cell potential when [Zn2+]=0.7 M and [Sn2+]=1.3 M ?arrow_forward
- A galvanic (voltaic) cell consists of an electrode composed of iron in a 1.0 M1.0 M iron(II) ion solution and another electrode composed of copper in a 1.0 M1.0 M copper(I) ion solution, connected by a salt bridge. Calculate the standard potential for this cell at 25 °C.25 °C. Refer to the list of standard reduction potentials.arrow_forwardA certain half-reaction has a standard reduction potential E=+0.21 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must provide at least 1.00 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the anode of the cell. Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have? Data O yes, there is a minimum. E red = v If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. O no minimum Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have? O yes, there is naximum. Pred = Iv If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. no maximum By using the information…arrow_forwardThe electrochemical cell Cu|Cu 2+||Al 3+|Al has a potential of –1.997 V under standard conditions. What is the standard reduction potential for the reaction of Al 3+ Al?arrow_forward
- Find the voltage of the cell if the right half-cell contains 0.330 M AgNO₃ (aq) and the left half-cell contains 0.115 M Cu(NO₃)₂ (aq). Express your answer to three significant figures.arrow_forwardWrite the balanced chemical equation for the spontaneous redox reaction. Include states of matter. Calculate the standard cell potential. If the initial concentrations of Zn2+ and of OH– are 1.0 × 10–7 and 2.0 × 10–7, respectively, calculate the cell potential after the Zn2+ concentration has increased by a factor of 100. At this point, what percentage of the initial voltage remains?arrow_forwardA galvanic cell at a temperature of 25.0 °C is powered by the following redox reaction: 2Cr³+ (aq) + 3 Ca(s) → 2Cr(s) + 3Ca²+ (aq) Suppose the cell is prepared with 6.35 M Cr³+ in one half-cell and 0.492 M Ca²+ in the other half. Calculate the cell voltage under these conditions. Cr³+ (aq) + 3e → Cr(s) Ca²+ (aq) + 2e →→ Ca(s) There are 6 galvanic cell. Er The standard cell potential (E°) for this galvanic cell is +2.124 red = -0.744 V Ered= -2.868 V volatage is 2.15 Under these conditions, the reaction quotient is moles of electrons transferred during to operate this V V. 0.00295 In order to increase the cell voltage for this cell ✔ [ Select ] V. and the cell It is impossible to change the voltage Not enough information Q>1 Q<1 3arrow_forward
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