Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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A Stirling cycle is a thermodynamic cycle similar to the Carnot cycle and is defined by the following processes.

    • -> 2: Isothermal expansion
    • -> 3: isochoric cooling
    • -> 4: isothermal heating
    • -> 1: isochoric heating


    • Solve the graph for  a Stirling cycle with the given information in which 50g of Ar (treated as an ideal gas) is isothermally expanded from 4L to 16L at a temperature of 700K. The sample is then undergoes isochoric cooling to 298K.  The sample is then isothermally compressed to 3L and finally undergoes isochoric heating back to 700K. 
Below is a table that needs to be completed, commonly featuring in thermodynamic studies. The table is labeled to show changes in different thermodynamic quantities across various processes. It is structured as follows:

**Table Columns:**
1. **Process**: Displays the initial and final states involved in the thermodynamic process.
2. **ΔA (kJ)**: Change in Helmholtz free energy, expressed in kilojoules.
3. **ΔG (kJ)**: Change in Gibbs free energy, expressed in kilojoules.
4. **ΔU (kJ)**: Change in internal energy, expressed in kilojoules.
5. **ΔH (kJ)**: Change in enthalpy, expressed in kilojoules.
6. **ΔS (J/K)**: Change in entropy, expressed in joules per Kelvin.

**Table Rows:**
- **1 ➞ 2**: Represents the transition from state 1 to state 2.
- **2 ➞ 3**: Represents the transition from state 2 to state 3.
- **3 ➞ 4**: Represents the transition from state 3 to state 4.
- **4 ➞ 1**: Represents the transition from state 4 back to state 1.

This table is to be filled out by calculating the changes in the thermodynamic properties for each respective process.
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Transcribed Image Text:Below is a table that needs to be completed, commonly featuring in thermodynamic studies. The table is labeled to show changes in different thermodynamic quantities across various processes. It is structured as follows: **Table Columns:** 1. **Process**: Displays the initial and final states involved in the thermodynamic process. 2. **ΔA (kJ)**: Change in Helmholtz free energy, expressed in kilojoules. 3. **ΔG (kJ)**: Change in Gibbs free energy, expressed in kilojoules. 4. **ΔU (kJ)**: Change in internal energy, expressed in kilojoules. 5. **ΔH (kJ)**: Change in enthalpy, expressed in kilojoules. 6. **ΔS (J/K)**: Change in entropy, expressed in joules per Kelvin. **Table Rows:** - **1 ➞ 2**: Represents the transition from state 1 to state 2. - **2 ➞ 3**: Represents the transition from state 2 to state 3. - **3 ➞ 4**: Represents the transition from state 3 to state 4. - **4 ➞ 1**: Represents the transition from state 4 back to state 1. This table is to be filled out by calculating the changes in the thermodynamic properties for each respective process.
The table below presents the states of a gas under different conditions of pressure, volume, and temperature. The values are given in standard units: pressure in atmospheres (atm), volume in liters (L), and temperature in Kelvin (K).

| **State** | **P (atm)** | **V (L)** | **T (K)** |
|-----------|-------------|-----------|-----------|
| 1         | 17.93       | 4         | 700       |
| 2         | 4.48        | 16        | 700       |
| 3         | 1.90        | 16        | 298       |
| 4         | 10.18       | 3         | 298       |

This data can be used to study the relationships described by the ideal gas law, which relates pressure, volume, and temperature of a gas.
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Transcribed Image Text:The table below presents the states of a gas under different conditions of pressure, volume, and temperature. The values are given in standard units: pressure in atmospheres (atm), volume in liters (L), and temperature in Kelvin (K). | **State** | **P (atm)** | **V (L)** | **T (K)** | |-----------|-------------|-----------|-----------| | 1 | 17.93 | 4 | 700 | | 2 | 4.48 | 16 | 700 | | 3 | 1.90 | 16 | 298 | | 4 | 10.18 | 3 | 298 | This data can be used to study the relationships described by the ideal gas law, which relates pressure, volume, and temperature of a gas.
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