A solution containing a mixture of metal cations was treated as outlined. 1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off. 2. H₂S was bubbled through the acidic solution. No precipitate formed. 3. The pH was raised to about 9 and H₂S was again bubbled through the solution. A precipitate formed and was filtered off. 4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off. What can be said about the presence of each of these groups of cations in the original solution? Cation group Ag+, Pb²+, Hg2+ Bi³ +, Cd²+, Cu²+, Hg²+, Pb²+, Sb³ +, Sn²+, Sn4+ Al³+, Co²+, Cr³+, Fe²+, Fe³+, Ni²+, Mn²+, Zn²+ Ba²+, Ca²+, Mg2+, Sr² + Li+, Na+, K+, NH Description form insoluble chlorides form acid-insoluble sulfides form base-insoluble sulfides or hydroxides form insoluble carbonates completely soluble Present in the original solution?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter19: The Chemistry Of The Main-group Elements
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Problem 88QRT
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A solution containing a mixture of metal cations was treated as outlined.
1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off.
2. H₂S was bubbled through the acidic solution. No precipitate formed.
3. The pH was raised to about 9 and H₂S was again bubbled through the solution. A precipitate formed and was filtered off.
4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off.
What can be said about the presence of each of these groups of cations in the original solution?
Cation group
Ag+, Pb²+, Hg2+
2
Bi³ +, Cd²+, Cu²+, Hg² +,
Pb²+, Sb³ +, Sn²+, Sn4+
Al³+, Co²+, Cr³+, Fe²+,
Fe³+, Ni²+, Mn²+,
₁²+. Zn²+
Ba²+, Ca²+, Mg²+, Sr² +
Li+, Na+, K+, NH+
Description
form insoluble chlorides
form acid-insoluble sulfides
form base-insoluble sulfides
or hydroxides
form insoluble carbonates
completely soluble
Present in the original solution?
Transcribed Image Text:A solution containing a mixture of metal cations was treated as outlined. 1. Dilute HCl was added and a precipitate formed. The precipitate was filtered off. 2. H₂S was bubbled through the acidic solution. No precipitate formed. 3. The pH was raised to about 9 and H₂S was again bubbled through the solution. A precipitate formed and was filtered off. 4. Finally, sodium carbonate was added to the filtered solution. A precipitate formed and was filtered off. What can be said about the presence of each of these groups of cations in the original solution? Cation group Ag+, Pb²+, Hg2+ 2 Bi³ +, Cd²+, Cu²+, Hg² +, Pb²+, Sb³ +, Sn²+, Sn4+ Al³+, Co²+, Cr³+, Fe²+, Fe³+, Ni²+, Mn²+, ₁²+. Zn²+ Ba²+, Ca²+, Mg²+, Sr² + Li+, Na+, K+, NH+ Description form insoluble chlorides form acid-insoluble sulfides form base-insoluble sulfides or hydroxides form insoluble carbonates completely soluble Present in the original solution?
Answer Bank
unknown
None of these ions were
present.
All of these ions were
present.
At least one of these ions
was present.
Transcribed Image Text:Answer Bank unknown None of these ions were present. All of these ions were present. At least one of these ions was present.
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