A proposed mechanism is shown below: (CH3)3CB1(aq) → (CH3)3C*(aq) + Br (aq) slow (CH3);C*(aq) + H20(1) (CH3)3COH2 (aq) (CH3)3COH2*(aq) fast > (CH3)3COH2 (aq) H*(aq) + (CH3)3COH(aq) fast Experimentally, a plot of In[(CH3)3CBr] vs. time gives a straight line with a slope of -0.0215 s-1 Consider the following statements, and then select the best response belov i. The overall reaction is (CH3)3CB|(aq) + H2O(1) (CH3)3COH(aq) + Br (aq) ii. The only intermediate is (CH3)3COH2*(aq). iii. The mechanism is consistent with the experimental data. O Only statement (iii) is true. O None of the statements are true. O Only statement (ii) is true. Only two statements are true. O Only statement (i) is true.

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Chapter1: Chemical Foundations
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A proposed mechanism is shown below:
(CH3)3CBr(aq) → (CH3)3C*(aq) + Br (aq)
slow
(CH3)3C*(aq) + H2O(1) → (CH3)3COH,*(aq)
fast
(CH3)3COH2*(aq) H*(aq) + (CH3)3COH(aq) fast
Experimentally, a plot of In[(CH3)3CBr] vs. time gives a straight line with a
slope of -0.0215 s-1
Consider the following statements, and then select the best response below.
i. The overall reaction is (CH3)3CBr(aq) + H2O(1) (CH3)3COH(aq) + Br
(aq)
ii. The only intermediate is (CH3)3COH2*(aq).
iii. The mechanism is consistent with the experimental data.
O Only statement (iii) is true.
O None of the statements are true.
O Only statement (ii) is true.
Only two statements are true.
O Only statement (i) is true.
Transcribed Image Text:A proposed mechanism is shown below: (CH3)3CBr(aq) → (CH3)3C*(aq) + Br (aq) slow (CH3)3C*(aq) + H2O(1) → (CH3)3COH,*(aq) fast (CH3)3COH2*(aq) H*(aq) + (CH3)3COH(aq) fast Experimentally, a plot of In[(CH3)3CBr] vs. time gives a straight line with a slope of -0.0215 s-1 Consider the following statements, and then select the best response below. i. The overall reaction is (CH3)3CBr(aq) + H2O(1) (CH3)3COH(aq) + Br (aq) ii. The only intermediate is (CH3)3COH2*(aq). iii. The mechanism is consistent with the experimental data. O Only statement (iii) is true. O None of the statements are true. O Only statement (ii) is true. Only two statements are true. O Only statement (i) is true.
Which of the following statements is true about collision theory?
O The orientation factor, p, for most molecular collisions is greater than 1.
O An increase in temperature causes an increase in reaction rate primarily because
the greater average speed causes the molecules collide more often.
O Each collision of reactant molecules results in a reaction occurring.
O An increase in the concentration of the reactants causes an increase in reaction
rate because the energy of the collisions increases.
O In the elementary reaction A + B
reactant doubles the overall collision frequency.
→ AB , doubling the concentration of a
Transcribed Image Text:Which of the following statements is true about collision theory? O The orientation factor, p, for most molecular collisions is greater than 1. O An increase in temperature causes an increase in reaction rate primarily because the greater average speed causes the molecules collide more often. O Each collision of reactant molecules results in a reaction occurring. O An increase in the concentration of the reactants causes an increase in reaction rate because the energy of the collisions increases. O In the elementary reaction A + B reactant doubles the overall collision frequency. → AB , doubling the concentration of a
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