A MO scheme for CO2 is shown below. Fill in the electrons for both the atoms and the molecule. Notice that since there are 2 oxygens, there are six p orbitals and two s orbitals associated with the right hand column of the MO scheme. Determine which orbitals are bonding vs. nonbonding, vs. antibonding and calculate the bond order. Notice that the names of the MO’s are no longer s and p - they have other names. (Hint: bonding vs. antibonding vs. nonbonding can be figured out based on the energy of the MOs and the positioning of the dashed lines.) Compare the bond order to the valence bond picture of CO2, [O=C=O]. How are they related?

Chemistry: An Atoms First Approach
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Chapter1: Chemical Foundations
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A MO scheme for CO2 is shown below. Fill in the electrons for both the atoms and the molecule. Notice that since there are 2 oxygens, there are six p orbitals and two s orbitals associated with the right hand column of the MO scheme. Determine which orbitals are bonding vs. nonbonding, vs. antibonding and calculate the bond order. Notice that the names of the MO’s are no longer s and p - they have other names. (Hint: bonding vs. antibonding vs. nonbonding can be figured out based on the energy of the MOs and the positioning of the dashed lines.) Compare the bond order to the valence bond picture of CO2, [O=C=O]. How are they related?

2 0
со,
C
4bu
4ag
2b3u 2b2u
2p
2p
1b2g 1b3g
1b3u 1b2u,
2s
3biu
Зад
2s
2bju
2ag
Transcribed Image Text:2 0 со, C 4bu 4ag 2b3u 2b2u 2p 2p 1b2g 1b3g 1b3u 1b2u, 2s 3biu Зад 2s 2bju 2ag
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To identify the bonding, antibonding and non-bonding orbitals of the carbon dioxide given that the molecular orbital diagram of carbon dioxide will be as follows: 

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