A given ligand is tetradentate. How many ligand donor atoms does it have? Enter your answer as a number. What is the coordination number of a coordination complex that has three of these ligands (and no others)? Enter your answer as a number.

A given ligand is tetradentate. How many ligand donor atoms does it have? Enter your answer as a number. What is the coordination number of a coordination complex that has three of these ligands (and no others)? Enter your answer as a number.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: So I am working with an octahedral complex that has two weak field ligands (Cl) and 4 strong field…

Q: Explain the formation of complexes/coordination compounds

Q: The compound formula is [Al(OH)&]Clh 1. Indicate central ion and its oxidation number. 2. Write down…

A: Coordination compounds: The compounds having coordination covalent bonds which form when metal ions…

Q: An octahedral complex is determined to be of the "strong field" type. It is determined that the…

A: In an octahedral complex, d-orbital splitting is shown below.

Q: All the following statements are correct EXCEPT: a. The pattern of d orbital splitting is…

A: In coordination chemistry, central metal ion is bonded to ligand. Ligand donate electrons to central…

Q: 10: 14) Recall that the bidentate ligand, ox² = Draw the structure of Fe(ox)(NH₂). Draw the metal…

A: A bidentate ligand is one that is capable to donate two pairs of lone pairs to the central atom.…

Q: T 4. Write the formula for each of the following ions or compounds. These are coordination…

Q: Draw the Lewis diagrams for each ligand. Indicate the lone pair(s) that may be donated to the metal.…

A: Lewis structures are the structures showing arrangement of valence electrons in an atom or a…

Q: Naming complex anions with one type of ligand Write the chemical formula of the following complex…

A: 1. Dicarbonatoferrate(III):"Ferrate(III)" indicates the central metal ion is iron (Fe) with an…

Q: 4. For each of the following metal complexes determine the formal oxidation state, d" electron…

A: Since you have asked a question with multiple subparts we will answer the first three for you. To…

Q: NH NH, NH, Terpyridyl (terpy) Bisethylenetriamine (tris) How do you expect these molecules to…

A: Denticity refers to the number of donor groups in a single ligand that bind to a central atom in a…

Q: Draw all possible resonance structures for each of the following ligands. Indicate the formal charge…

Q: Match each of the terms with their definitions. a ligand that can form two bonds (donate two…

A: a ligand that can form two bonds (donate two electron pairs) to a metal ion - bidentate ligand a…

Q: 2. Ferrocyanide and ferricyanide are a particular kind of transition metal complex. State what that…

Q: What is the coordination number, ligand number, donor atom number, bidentate ligand number, complex…

A: The complex given is ethylenediaminetetraacetate Chromate(III).

Q: complex? a. The temperature at which the pure metal melts b. the energy gap between orbitals…

A: As we know color of metal in complex compound depends upon electron transition between energy…

Q: An octahedral complex is determined to be of the "weak field" type. It is determined that the metal…

A: Answer:When ligands approach the central metal ion they divide the degenrated d-orbitals into…

Q: Consider the formation of a complex between one silver cation and four thiocyanate (SCN) ligands.…

A: To determine the overall charge on the complex formed between one silver cation and four thiocyanate…

Q: Draw all the isomers of an octahedral complex having four different monodentate ligands.

A: The isomers of an octahedral complex having four different monodentate ligands can be drawn as…

Q: How many unpaired electrons are there in a strong field iron(II) octahedral complex? 0 1 2 3

A: Since you have asked multiple type questions, we will solve only first questions for you. If you…

Q: Consider this metal complex: Br 5 Complex A Now decide whether each complex in the table below is…

A: ♧ In complex A, number of Br atoms = 2Number of Cl atoms = 4Two Br atoms are cis with respect to…

Q: A given ligand is tetradentate. If a transition metal cation complexed (coordinate covalently…

A: Here we are required to find the coordination number of resulting hypothetical complex ion

Q: For which of the following cases of octahedral complexes should we consider the possibility of…

A: The complexes in which plane of symmetry is present are supposed to be optically inactive compounds…

Q: Using crystal field theory, draw an electron box energy level diagram for the valence d orbitals on…

A: IntroductionCreate an energy level diagram for the valence d orbitals on the manganese atom in a…

Q: A tetrahedral complex is determined to be of the "weak field" type. It is determined that the metal…

A: Tetrahedral complex, there are four ligands attached to the central metal. The d orbitals also split…

Q: Which statements are true regarding crystal field theory?A. The eg orbitals are higher in energy in…

A: The objective of the question is to identify the correct statements regarding the crystal field…

Q: Consider the [CoBr214]4 complex from the standpoint of the crystal field theory. Sketch the d…

Q: Determine the oxidation state of the transition metal in each of these coordination compounds.…

Q: ligand bonding, that is, what percentage ionic and what percentage covalent are the bonds?

A: Given complex: [FeCl4]- To find:metal oxidation statecharge on ligandNature of ligand…

Q: Compare the ligand field strengths of CO and Cl, in terms of the types of bonds in which they can be…

A: CO is Sigma donor and pi acceptor ligand while Cl is only Sigma donor ligand .thus there type of…

Q: 1. types of ligands present in the compounds. 2. Coordination number of the compounds ( how to look…

A: Ligands are those species which are characterised by electron donors to the empty d orbitals of a…

Q: What is a chelator ligand? A ligand that only binds to a metal at a single point A ligand with…

A: * Multiple donor atom * Donor atom can be same or different* Form ring with metal

Q: A CO ligand can coordinate either via the carbon atom or the oxygen atom. What type of isomerism…

A: Given:

Q: Which of the following statements is TRUE about the complex ion/coordination compound formation? a.…

A: Coordination complexes are the compounds which contents Central metal atom surrounded by array of…

Q: Which of the following ligands are capable of linkage isomerism? Explain your answer. (Draw a 2.…

A: We have to tell which of these ligands are capable of linkage isomerism so the ligand which are…

Q: In the following blanks, write the chemical formula of the named coordination compounds. Use the…

A: While writing the formula of complex compounds we follow certain rules as written below: (i). If the…

Q: How many isomers (include geometric and optical) are there for an octahedral complex where the metal…

A: Given : the molecule is octahedral complex and four different monodentate ligand and one bidentate…

Q: Crystal Field Theory: Answer the question and provide complete solution a. Draw the electronic…

A: Answer Crystal field Theory ⇒a NiCl63- x=6=-3 x=+3

Q: 1. Identify the coordination number, oxidation state, ligand, and donor atom. 2. Write the chemical…

A: 1.

Q: How many unpaired electrons are there in the complex ion [CO(NO3)5]¯? For this in the nitrate…

A: Given , Initial amount of substance = 60mg t1/2 = 6 h Total time = 24 h N ❓ In question 2 Since…

Q: Coordination compounds, coordination sphere, central atom, ligand and coordination number concepts.…

A: In this question, we have to find out the correct answer of given problem by the help of…

Q: 18. K3[Fe(CN)6], The oxidation state Off. the metal atom is _ and the coordination number of the…

A: Given coordination complex = K3[Fe(CN)6] Here, K = Metal which lies in the ionization sphere. Fe…

Q: Dimethyldithiocarbamate (abbreviated as dmdtc) is an anionic bidentate ligand with a chemical…

A: dmdtc is a bidentate strong field anionic ligand.

Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

A given ligand is tetradentate. How many
ligand donor atoms does it have? Enter
your answer as a number.
What is the coordination number of a
coordination complex that has three of
these ligands (and no others)? Enter your
answer as a number.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1: The main aim of the question

VIEW

Step 2: Understanding the concepts related to the ligand

VIEW

Solution

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 16 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Select the INCORRECT statement about the theories of electronic structure from the followings?
Which of the following statements is not true? A. Coordination Chemistry is the science concerned with the interactions of organic and inorganic ligands with metal centers. B. Coordination compounds are composed of a metal atom or ion and one or more ligands (atoms, ions, or molecules) that donate electrons to the metal. C. Coordination compounds include organometallic compounds. D. The modern theory of coordination chemistry is based largely on the work of Alfred Werner. E. Coordination compounds are examples of Brønsted-Lowry acid-base adducts.
Dimethyldithiocarbamate (abbreviated as dmdtc) is an anionic bidentate ligand with a chemical formula (S2CNMe2)- - where Me stands for methyl group (-CH3). In the photo above, this ligand coordinates to a metal through its 2 sulfur atoms (where M represents a metal). When three dmdtc ligands bind to a ferric ion (Fe3+), a stable coordination complex called ferbam is formed. Given this information, answer / identify the following. complex geometry hybridization type of the central atom coordination number
For finding the oxidation state of metal atom in coordination compound, charge on the ligand should be known. Chloro ligand has -1 charge. amino ligand is neutral. [MnCl2(NH3)4]* Let x is the oxidation state of metal. Above compound has +1 charge on it x+2(-1)+4(0) = 1 x-2+0=1 x =1+2= 3 So, oxidation of Mn metal = 3 [Co(CN)4(H20)2]²- x+ 4(-1) + 2(0) = -2 x= -2 +4 = 2 Oxidation state of Co metal = 2 [Fe(OH)sCO]3- x+5(-1) + 0 = -3 x - 5 = -3 x= -3 +5= 2 So, oxidation state of Fe metal = 2
Consider this metal complex: Br Br Cl C1 8 \. Br Complex A Now decide whether each complex in the table below is another example of A, an isomer of A, or an entirely different chemical compound. Complex Br Br Br Br 8 J J J Cl Br 8 8 V C1 Br 8 Cl Br 5 J 2 Br 3- This complex is ... O the same as A ... an isomer of A ... a different compound. ...the same as A O an isomer of A ... a different compound. O ... the same as A ...an isomer of A O a different compound. O ... the same as A O ... an isomer of A ... a different compound. M
Consider the coordination complex [Cr(OH₂)3C13] Br3 Identify the ligands by name (include the word "ion" at the end for all ions): What is the charge on the coordination complex? Enter the sign then the numeric value (+2, -2, etc.) What is the oxidation state of the Cr ion? Enter the sign then the numeric value (+2, -2, etc.) What is the coordination number for the complex ion? Enter your answer as a number.
True or false: Coordination complexes are called such because they consist of ions or molecules that are bound to ha halogenated metal
Which statements are true regarding ligands? Select all that apply. Ligands donate all electrons involved in bonds they form with metal cations. Ligands are electron pair acceptors in coordination complexes. Ligands act as Lewis bases in coordination complexes. Ligands form ionic bonds with transition metals. All ligands with two lone pairs are bidentate. A ligand that can donate more than one electron pair to a metal cation is called a chelate. One ligand can donate only one lone pair to a metal cation.
The following neutral molecules or ionic species are considered: CIO, CNO, NH3, O2, CH4, H2NCH2CH2NH2 1. What is the condition for a species (molecule or ion) to form a coordination complex? 2. In the list above, indicate which species can behave as ligands. Are they polydentate, ambidentate Ligands and / or bridging ligands?
You are comparing two coordination complexes that have the same molecular shape and central metal cation. Complex A has only chloride ligands and Complex B had only CO ligands. Which statements are true regarding the complexes? Select all that apply. Complex A has the smaller crystal field splitting. Light of higher frequency is required to promote an electron from the lower to the higher d orbitals in complex A relative to complex B. The light emitted as a photon is released to relax an electron from higher to lower energy d orbitals has a longer wavelength for complex A. Light of higher frequency is required to promote an electron from the lower to the higher d orbitals in complex B relative to complex A. The light emitted as a photon is released to relax an electron from higher to lower energy d orbitals has a longer wavelength for complex B. Complex B has the smaller crystal field splitting.
A. Draw MX4Y2 where “M” is the metal and “X” and “Y” are ligands. Draw the “Y” ligands trans. Do not worry about the oxidation state of the metal or the overall charge of the complex ion. B. Ethylenediamine, H2NCH2CH2NH2, cannot bind “trans” to a metal with an octahedral shape. It must bind “cis”. On the other hand, a ligand with the structural formula H2PCH2CH2CH2CH2CH2PH2 can bind “trans”.
Consider the complex ion [Pd(NH3)2CI2]. The coordination number is type your answer.. The oxidation number of palladium is type your answer. The correct systematic name of the complex is choose your answer.