a) Gibbs free energy, G (J*mole^-1) b) Entropy, S (J*mole^-1*K^-1) c) Enthalpy, H (J*mole^-1) d) The fugacity values of benzene and ethanol in solution (kPa)
a) Gibbs free energy, G (J*mole^-1) b) Entropy, S (J*mole^-1*K^-1) c) Enthalpy, H (J*mole^-1) d) The fugacity values of benzene and ethanol in solution (kPa)
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Related questions
Question
![A mixture of benzene (1) and ethanol (2) at 45 ° C, a combination of vapor and liquid phases
It is in equilibrium at 0.4093 bar pressure, and the ethanol in the liquid and vapor phases
their compositions (as mole fraction) have values of 0.5284 and 0.4101, respectively. It is
accepted that the vapor phase under conditions behaves like an ideal gas. The following of the
vapor phase
Calculate the properties:
a) Gibbs free energy, G (J*mole^-1)
b) Entropy, S (J*mole^-1*K^-1)
c) Enthalpy, H (J*mole^-1)
d) The fugacity values of benzene and ethanol in solution (kPa)
*Take the enthalpy and the entropy values as zero for benzene and ethanol in ideal gas state,
saturated vapor form at 273 K
ig
E= A +BT + CT².
R
*The saturated vapor pressure values can be calculated in accordance with the Antoine
equation.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff35445c6-592a-4e21-99f0-d869ab0034d6%2F29ea2fbb-9b92-4f6d-8a06-320398bc710d%2Fgzlvgcm_processed.png&w=3840&q=75)
Transcribed Image Text:A mixture of benzene (1) and ethanol (2) at 45 ° C, a combination of vapor and liquid phases
It is in equilibrium at 0.4093 bar pressure, and the ethanol in the liquid and vapor phases
their compositions (as mole fraction) have values of 0.5284 and 0.4101, respectively. It is
accepted that the vapor phase under conditions behaves like an ideal gas. The following of the
vapor phase
Calculate the properties:
a) Gibbs free energy, G (J*mole^-1)
b) Entropy, S (J*mole^-1*K^-1)
c) Enthalpy, H (J*mole^-1)
d) The fugacity values of benzene and ethanol in solution (kPa)
*Take the enthalpy and the entropy values as zero for benzene and ethanol in ideal gas state,
saturated vapor form at 273 K
ig
E= A +BT + CT².
R
*The saturated vapor pressure values can be calculated in accordance with the Antoine
equation.
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