
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Transcribed Image Text:### Question 5
A dilute solution of bromine in carbon tetrachloride behaves as an **ideal-dilute solution**. The vapor pressure of pure CCl₄ is 33.85 Torr at 298 K. The Henry's law constant when the concentration of Br₂ is expressed as a mole fraction is 122.36 Torr. If the mole fraction of Br₂ is 0.02, and the conditions of the ideal-dilute solution are satisfied at this concentration, calculate the following:
**Instruction:** Please enter all answers with **2 decimals**. For example, 0.0169 is written as 0.02.
1. **Vapor pressure of each component:**
- \( P(\text{CCl}_4, \, \text{Torr}) = 33.14 \)
- \( P(\text{Br}_2, \, \text{Torr}) = 2.45 \)
2. **The total pressure, \( P(\text{total, Torr}) = 35.62 \)**
3. **The composition of the vapor phase:**
- \( y(\text{CCl}_4) = 0.93 \)
- \( y(\text{Br}_2) = 0.07 \)
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