A Daniell cell in the standard state is presented as Zn(s) | Zn2+ (1,000 M) || Cu2+ (1,000 M) | Cu(s) E°cell = 1.10 V. a) By how many percent has the concentration of the copper ions decreased when the potential of the cell has decreased by 10%? What is the concentration of zinc ions? b) Consider the diagrams below. According to your calculations, what is the optimum pH range for the functioning of the Daniell cell? Comment on why.

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A Daniell cell in the standard state is presented as
Zn(s) | Zn2+ (1,000 M) || Cu2+ (1,000 M) | Cu(s) E°cell = 1.10 V.
a) By how many percent has the concentration of the copper ions decreased when the potential of the cell has
decreased by 10%? What is the concentration of zinc ions?
b) Consider the diagrams below. According to your calculations, what is the optimum pH range for the
functioning of the Daniell cell? Comment on why.

t= 25°C
[Zn²+]TOT = 0.00
Log Conc.
0
-2
-6
-8
H+
2
Cu²+
Cu₂(OH)₂2+
CUOHT
Cu3(OH)42+
4
6
pH
[Cu²+]TOT =
8
CuO(cr)
10
1.00 M
OH-
Cu(OH)3
Cu(OH)4²-
Cu(OH)2
12
t= 25°C
[Zn2+]TOT = 2.00 M
Log Conc.
0
-2
-4
-6
-8
H+
2
Zn2+
Zn₂0H³+
ZROH+
Zn4(OH)44+
4
6
PH
[Cu2+]TOT = 0.00
8
ZnO(cr)
10
OH-
Zn(OH)3
Zn(OH)₂
Zn(OH)4²
Zn₂(OH) 6²-
22(4)
12
Transcribed Image Text:t= 25°C [Zn²+]TOT = 0.00 Log Conc. 0 -2 -6 -8 H+ 2 Cu²+ Cu₂(OH)₂2+ CUOHT Cu3(OH)42+ 4 6 pH [Cu²+]TOT = 8 CuO(cr) 10 1.00 M OH- Cu(OH)3 Cu(OH)4²- Cu(OH)2 12 t= 25°C [Zn2+]TOT = 2.00 M Log Conc. 0 -2 -4 -6 -8 H+ 2 Zn2+ Zn₂0H³+ ZROH+ Zn4(OH)44+ 4 6 PH [Cu2+]TOT = 0.00 8 ZnO(cr) 10 OH- Zn(OH)3 Zn(OH)₂ Zn(OH)4² Zn₂(OH) 6²- 22(4) 12
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