Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- (a) Choose all of the statements from below which correctly describe issues pertaining to the relationship between the emf of a reaction and its Gibbs free energy change. ____The Gibbs free energy change and emf values of a reaction have opposite algebraic signs (+ vs. -).____A Gibbs free energy change involves moles of substances whereas an emf involves coulombs of electrons.____A coulomb of particles is more particles than a mole of particles.____Faraday's constant is not used to interconvert a Gibbs free energy change and a reaction emf.____A Gibbs free energy change involves coulombs of substances whereas an emf involves moles of electrons.Calculate the standard Gibbs free energy changes at 25 oC for each of the reactions shown below using the Eo values given. Select whether each of these reactions is nonspontaneous, at equilibrium, or spontaneous under standard conditions. (a) 1 Al3+(aq) + 3 Ag(s) 1 Al(s) + 3 Ag+(aq) Eo = -2.459 V Go =________ kJ/mol ____nonspontaneous…arrow_forward1. Given the following reactions and data, use addition (similar to Hess's Law) to calculate AG° for H3PO4 (s). (Hint: The overall reaction is for the formation of 1 mol of H3PO4 (s) from elements in their natural state (elemental phosphorus is P4 (s)). PA () + 5 02@ → P,O10 (5) AG; - 2698 kJ P,O10 (9) + 6 H0 m → 4 H3P04 () H2 ( + ½ 02 (2) → H;O @ AG° = – 396 kJ - 228.6 kJ AG; : AG vap H,O 0 → H2O @ 8.6 kJ Required work: * rewrite the reactions above in the correct direction, using multipliers to change coefficients and modify AG° values if necessary * show that after cancelling, the sum of your reactions gives the desired overall reaction Write the goal equation first?arrow_forwardFrom the enthalpies of reaction 2C(s) + O2 (9) → 2C0(g) 2C(s) + O2 (9) + 4H2 (g) → 2CH3 OH(g) AH ΔΗ :-221.0kJ %3| :-402.4kJ calculate AH for the reaction CO(g) + 2H2 (g) → CH3 OH(g) Express your answer to three significant figures with the appropriate units.arrow_forward
- The following reaction has a AG° value of +8.43 kJ/mol at 25 °C. HA(aq) + H20(1) =H;O*(aq) + A (aq) Calculate the KA for the acid HA.arrow_forwardCalculate AGºrxn for the reaction: BaCO3(s)→BaO(s)+CO₂(g) Use the following reactions and given AGºrxn values: Ba(s)+CO₂(g)+1/2O2(g) →BaCO3(s) AG°rxn=-1134.4kJ 2Ba(s)+O₂(g)→2BaO(s), AGºrxn=-520.3kJ BaCO3(s)→BaO(s)+CO₂(g). AGºrxn =arrow_forwardMISSED THIS? Read Section 19.8 (Pages 871-877); Watch IWE 19.6. Liquid methanol burns in oxygen to form gaseous carbon dioxide and gaseous water. Substance H (kJ/mol) S° (J/(mol · K)) CH, OH (1) -238.6 126.8 O₂(g) 0 205.2 CO₂(g) -393.5 213.8 CO2(aq) -413.8 117.6 H₂O(g) -241.8 188.8 H₂O(1) -187.8 70.0 ▼ Part D where no represents the stoichiometric coefficients of the products, n, represents the st of the reactants, and Sº represents the standard entropies. AGxn= Calculate AG at 25°C. Express your answer in kilojoules to three significant figures. Submit = Provide Feedback 15] ΑΣΦ Request Answer Part E Complete previous part(s) [2(S° co₂(g)) + 4(S° H₂O(g))]- [2(S° CH₂OH()) + 3(S° 0₂(E [2(213.8 J/K)+4(188.8 J/K)] - [2(126.8 J/K) + 3(2 314 J/K MacBook Pro P Pearson ? kJ Copyright © 2023 Pearson Education Inc. All rights reserved. | Terms of Use | Privacy Policy | Permissions Contacarrow_forward
- Calculate AH for the following reaction: IXI C(s) +H,0(g)→Co(g) - H, (3) Use the following reactions and given AH values: C(s) + O2 (g)→CO, (g), AH- 393.5 kJ 20(g) + 02 (g)→2CO2(g), AH = -566.0 kJ 2H2 (g) + O2 (g)→2H2O(g). AH = -483.6 kJ Express your answer using four significant figures.arrow_forwardA critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction ATP(aq) + H, O(1) - ADP(aq) + HPO (aq) for which AGan = -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of AG, in a biological cell in which [ATP] = 5.0 mM, [ADP] = 0.40 mM, and (HPO = 5.0 mM. %3D %3D kJ/mol AGan = + TOOLS x10 Is the hydrolysis of ATP spontaneous under these conditions? O yes noarrow_forwardConsider the following reaction: 3C(s) + 3H2(g) → C3H6(g); AG°= 60.0 kJ and AS° =-256.7 J/K at 298 K What is the equilibrium constant and AH° at 298 K for this reaction? Express AH° in kJ and use 3 significant figures for both answers. AH° = kJ and Keq x 10arrow_forward
- The standard enthalpy of formation of SnCl₂ (s) is - 340 kJ/mol and that for SnCl4 (s) is-511 kJ/mol. From these data, we can calculate that for the reaction SnCl₂ (s) + Cl₂ (g) →→SnCl4 (s), the value of AH O cannot be determined as AH, for Cl₂ (g) is not given. O equals - 851 kJ. O equals + 171 kJ. O equals - 171 kJ.arrow_forward2H2 + 2 02 --> 2H2O, + 296 kj is an example of a(n) B.arrow_forward(Q70) Using the tabulated values from the text (located in Appendix G, beginning at p. 1211) calculate (and report in kJ) the standard Gibbs free energy (AG°rxn) for the net reaction that occurs during photosynthesis: 6 H2O (1) + 6 CO2 (g) --> C6H12O6 (s) + 6 O2 (g). The AG°; for glucose (C6H1206) is -1273.3 kJ/mol.arrow_forward
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