Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of
adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction
ATP(aq) + H,O(I)
ADP(aq) + HPO-(aq)
for which AGrxn
= -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of AGrxn in a biological cell in which
[ATP] = 5.0 mM, [ADP] = 0.40 mM, and [HPO-] = 5.0 mM.
AGrxn
kJ/mol
%D
Is the hydrolysis of ATP spontaneous under these conditions?
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Transcribed Image Text:A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction ATP(aq) + H,O(I) ADP(aq) + HPO-(aq) for which AGrxn = -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of AGrxn in a biological cell in which [ATP] = 5.0 mM, [ADP] = 0.40 mM, and [HPO-] = 5.0 mM. AGrxn kJ/mol %D Is the hydrolysis of ATP spontaneous under these conditions?
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