Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Imagine the diagram shown below is a 'good representation' of a titration curve for the titration of
20.0 mL of 0.10 M Na4A with 0.15 M HCI. Use this information to fill in the blanks below.
В
A
D
pH
F
H
Volume of HCI (mL)
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Transcribed Image Text:Imagine the diagram shown below is a 'good representation' of a titration curve for the titration of 20.0 mL of 0.10 M Na4A with 0.15 M HCI. Use this information to fill in the blanks below. В A D pH F H Volume of HCI (mL)
a) Consider: A4-(aq) + 2 H3O*(aq) →
H2A²(aq) + 2 H20(1).
This is the net ionic reaction that occurs between the beginning of the titration and to the
equivalence point. (Type in 1st, 2nd, 3rd or 4th.)
b) After point
along the titration curve, the analyte is just starting to gain the
4th proton.
(Турe in A, B, C..)
c) The point along the titration curve where concentrations of H2A2 and H3A are equal is
(Туре in A, B, C..)
d) Molecules and ions: H4A, H3A", H2A2, HA³- or A4-
Of the molecule and ions shown above, the molecule or ion that has the highest concentration
when 36.0 mL of 0.15 M HCI has been added is
(Do not use super- or
subscripts. Write H3A¯ as H3A-)
For H4A:
Ka1 = 2.5 x 10-2, Ka2 = 7.5 x 10-5, Ka3 = 9.2 x 10-9, and Ka4 = 4.3 x 10-13
%3D
e) The pH at midpoint 2 is
(Report your pH value to two sig figs.)
f) The value of Kb3 for A4 is
(Use two sig figs.) (Do not use superscripts,
subscripts or carets! Write 1.2 x 103 as 1.2x10-3 or 1.2e-3.)
expand button
Transcribed Image Text:a) Consider: A4-(aq) + 2 H3O*(aq) → H2A²(aq) + 2 H20(1). This is the net ionic reaction that occurs between the beginning of the titration and to the equivalence point. (Type in 1st, 2nd, 3rd or 4th.) b) After point along the titration curve, the analyte is just starting to gain the 4th proton. (Турe in A, B, C..) c) The point along the titration curve where concentrations of H2A2 and H3A are equal is (Туре in A, B, C..) d) Molecules and ions: H4A, H3A", H2A2, HA³- or A4- Of the molecule and ions shown above, the molecule or ion that has the highest concentration when 36.0 mL of 0.15 M HCI has been added is (Do not use super- or subscripts. Write H3A¯ as H3A-) For H4A: Ka1 = 2.5 x 10-2, Ka2 = 7.5 x 10-5, Ka3 = 9.2 x 10-9, and Ka4 = 4.3 x 10-13 %3D e) The pH at midpoint 2 is (Report your pH value to two sig figs.) f) The value of Kb3 for A4 is (Use two sig figs.) (Do not use superscripts, subscripts or carets! Write 1.2 x 103 as 1.2x10-3 or 1.2e-3.)
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