Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- 8arrow_forwardIn the following: Al³+ (aq) + 3e → Al(s) E° = -1.66 V Cr³+ (aq) + 3e → Cr(s) E° = -0.74 V What is the standard cell potential for the corresponding galvanic cell? 0.00 V O-0.92 V +2.40 V +0.92 V O-2.40 Varrow_forwardUse the tabulated half-cell potentials to calculate the standard cell potential for the following balanced redox reaction. 312(s)+2 Fe(s) → 2 Fe3+(aq) +61 (aq) 12(s)+2e 21-(aq) E°=+0.54 V Fe3+(aq) +3 e → Fe(s) E°=-0.04 V A) +0.29 V B) +0.50 V C) -0.50 V D) -0.58 V E) +0.58 Varrow_forward
- A chemist designs a galvanic cell from the following two half-reactions NO3(aq) + 4H+ (aq) + 3e → NO(g) + EO red = +0.96 V 2H₂0 (1) Cu2+ (aq) + e → Cut (aq) Ere red= +0.153 V The standard cell potential for this galvanic cell is [Select] The standard free energy for this galvanic cell is AG [Select] The equilibrium constant (K) for this galvanic cell is [Select] V..arrow_forwardA chemist designs a galvanic cell that uses these two half-reactions: half-reaction standard reduction potential Br,(1)+2e - 2 Br (aq) =+1.065 V ʼred MnO,(aq)+2 H,O(1)+3e MnO,(s)+4 ОН (аq) E=+0.59 V (red Answer the following questions about this cell. Write a balanced equation for the half-reaction that happens at the cathode. x10 Write a balanced equation for the half-reaction that happens at the anode. Write a balanced equation for the overall reaction that powers the cell. Be sure the reaction is spontaneous as written.arrow_forwardUse the standard reduction potentials given below to predict if a reaction will occur between Zn(s) and Cl2(g), when the two are brought in contact via standard half-cells in a voltaic cell. | Cl2(g) + 2e¯¯ →2C1¯¯ (aq) E Zn2+ = 1.360 V red (aq) + 2e → Zn(s) E = = -0.763 V red If a reaction will occur, write a balanced net ionic equation for the reaction, assuming that the product ions are in aqueous solution. If no reaction will occur, leave all boxes blank. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) + +arrow_forward
- A certain metal M forms a soluble nitrate salt MNO33 . Suppose the left half cell of a galvanic cell apparatus is filled with a 5.00M solution of MNO33 and the right half cell with a 25.0mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0°C. What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode.Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.arrow_forwardA certain half-reaction has a standard reduction potential Ered=-0.64 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 1.20 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. ロ→ロ 7² 0 Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell can have? yes, there is a minimum. = v If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. no minimum X S ? Is there a maximum standard reduction potential that the half-reaction used at the anode of this cell can have? O yes, there is a maximum. ☐v If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. no maximum By using the information in…arrow_forwardA chemist designs a galvanic cell that uses these two half-reactions: half-reaction |HNO₂(aq)+H*(aq)+e¯ - →>> NO(g) + H2O(l) Fe3+(aq)+e → Fe (aq) Fe2+(aq) Answer the following questions about this cell. standard reduction potential +0 Ε = +1.00 V 0 red Ered = +0.771 Varrow_forward
- Consider the following voltaic cellat 25°C: Al(s) | Al3*(0.20 M, aq) || Al3+(0.75 M, aq) | Al(s) If the standard reduction potential for the Al3+(aq) /Al(s) redox couple is -1.66 V, what is the overall cell reaction and the cell potential of the voltaic cell shown above? (Reference the cell as written above.) The overall cell reaction is Al3+(0.75 M, aq) AIS*(0.20 M, ag) and E°cell = +0.0113 V. There is no overall cell reaction and E°cell = 0.00 V. The overall cell reaction is Al3+(0.20 M, aq) Als*(0.75 M, aq) and E°cell = +0.0113 V. The overall cell reaction is Al3+(0.20 M, aq) →A13+(0.75 M, ag) and E°cell| = -0.0113 V. The overall cell reaction is Al3*(0.75 M, aq) →AI3*(0.20 M, aq) and E°cell = -0.0113 V. None of thesearrow_forward3. The oxidation of methanol, as described by the equation below, has a AG value of -937.9 kJ/mol. What is the standard cell potential for a methanol fuel cell? 2CH3OH +30₂ → 2CO₂ + 4H₂Oarrow_forward. Consider the oxidation-reduction reaction Mg (s) + Cu2+ (aq) → Mg2+ (aq) + Cu (s) Sketch a galvanic cell that uses this reaction. Which metal ion is reduced? Which metal is oxidized? What half-reaction takes place at the anode in the cell? What half-reaction takes place at the cathode?arrow_forward
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