A chemical manufacturer wants to try a new process for making a highly refined form of nickel(II) oxide from nickel(II) nitrate and sodium hydroxide as reactants. The byproducts (other products other than nickel(II) nitrate) are HNO3 and sodium nitrate. The product is used in making rechargeable Nickel Metal Hydride batteries (NiMH). The raw materials cost $2,000 per metric ton for nickel(II) nitrate and $900 per metric ton for sodium hydroxide. A metric ton is equal to 1,000 kg.
The first new method uses twice the mass of nickel(II) nitrate as sodium hydroxide and has a 90% yield, but refinement & waste processing only costs $25 per ton.
The other new method uses five times the mass of nickel(II) nitrate as sodium hydroxide, has a 99% yield, and refinement/waste processing only costs $10 per ton. Your group has been hired as a consulting firm to help the manufacturer decide whether to adopt one of the new processes and if so, which one to choose. What is your advice to the manufacturer? How did you reach your answer? What actional results (data or calculations) can you share with this manufacturer to help them decide on the best path?
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- 4. [Scrubber]. A coal-fired combustion system produces flue gas that contains particulate matter. To reduce the amount of particles, the flue gas is treated in a scrubber. The measurement of the mass and size of the particles at the inlet and outlet of the scrubber yielded the size distribution data given in the following table: Particle diameter [um] (size interval: dlower → dupper) 0.10.25 0.25 → 0.5 0.5 → 1.0 1.0→2.0 2.05.0 Formulas for question 4: . Particle mass at scrubber inlet [mg] 623 55.4 12.6 8.9 7.1 5.0 10 7.7 10 →30 6.6 30→ 50 4.3 The mass of particles in each size interval was measured on a basis of 1 m²³. 31.4 33.2 123 a) What is the overall efficiency of the scrubber? [Ans: noverall 96.7 %] b) Calculate the collection efficiency (na,i) of the scrubber and the particle geometric average diameter (dpi) for each size interval. Create a graph showing the variation of na,i with dp,i. (PTO) efficiency: nd,i (%) = - 394 775 1055 c) Calculate the mass-average diameter of the…arrow_forwardPure oxygen (O2) at high pressure is sometimes used in chemical processes instead of air to avoid the high cost of pressurizing all the N2 that inevitably comes with use of air as well as additional cost of capital equipment such as heat exchangers, reactors, etc. through which the (generally unnecessary) nitrogen flows. The decision of which to use (pure O2 or air) is based on the tradeoff between the cost of obtaining the pure O2 (via cryogenic distillation or membrane separation) versus the cost of all the unnecessary N2 running through the process. Your process utilizes O2 at -70°C and 10.2 atm absolute. If the mass flow rate of O2 is 8.0 kg/min, determine the volumetric flow rate of the O2 stream using (a) the ideal gas EOS and (b) the SRK EOS.arrow_forwardA chemical engineer is studying the following reaction: BF 3(aq)+NH3(aq) → BF ,NH3(aq) At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.3. The engineer charges ("fills") three reaction vessels with boron trifluoride and ammonia, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction expected change in concentration compound concentration vessel BE3 I decrease (no change) 0.48 M f increase NH3 I decrease (no change) 0.55 M f increase A BF,NH3 f increase I decrease (no change) 1.01 M 0.41 M f increase I decrease (no change) BF, NH3 I decrease (no change) 0.48 M f increase В BF,NH3 f increase I decrease (no change) 1.08 M BF3 I decrease (no change) 1.07 M ↑ increase NH3 I decrease (no change) 1.14 M f increase C…arrow_forward
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