A certain metal M forms a soluble nitrate salt M (NO3)2 Suppose the left half cell of a galvanic cell apparatus is filled with a 500. mM solution of M (NO3)₂ and the right half cell with a 5.00 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 25.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. Oleft 0 right X

A certain metal M forms a soluble sulfate salt MSO. Suppose the left half cell of a galvanic cell apparatus is filled with a 400. mM solution of 4' MSO, and the right half cell with a 4.00 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 20.0 °C. left olo x10 Which electrode will be positive? O right Ar What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.

A certain metal M forms a soluble sulfate salt M₂SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 3.50 M solution of M₂SO4 and the right half cell with a 35.0 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 40.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. 0 left right

A certain metal M forms a soluble sulfate salt M₂SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 2.50 M solution of M₂SO4 and the right half cell with a 1.25 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 40.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. 0 Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left right ☐ x10 X Ś

A certain metal M forms a soluble sulfate salt MSO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 200. mM solution of MSO4 and the right half cell with a 4.00 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 20.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. 0 left right x10 X S

A certain metal M forms a soluble nitrate salt M(NO3)2. Suppose the left half cell of a galvanic cell apparatus is filled with a 1.50 M solution of M(NO3)₂ and the right half cell with a 15.0 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. 0 Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left right X Ś ?

A certain metal M forms a soluble sulfate salt M,SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 22.5 mM solution of M,SO, and the right half cell with a 4.50 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 25.0 °C. O left Which electrode will be positive? O right What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.

A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG. • The equilibrium constant K at 25.0 °C. • The cell potential under standard conditions E His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 1. calculated quantities (Check the box next to any that are wrong.) cell AG K E A 77. kJ/mol -14 3.24 x 10 0.80 V 119. kJ/mol 20 7.05 x 10 -1.23 V 60. kJ/mol -11 3.08 x 10 -0.62 V

A certain metal M forms a soluble nitrate salt M{NO3), Suppose the left half cell of a galvanic cell apparatus is filled with a 15.0 mM 3 solution of M(NO,), and the right half cell with a 1.50 M solution of the same substance. Electrodes made of M are dipped into both 3 solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. left x10 Which electrode will be positive? right What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.

A certain metal M forms a soluble sulfate salt M2(SO4)3. Suppose the left half cell of a galvanic cell apparatus is filled with a 3.50 mM solution of M2(SO4)3 and the right half cell with a 3.50 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. U ○ left x10 O right ⑤