(a) Account for the following :(i) Cl – CH2COOH is a stronger acid than CH3COOH.(ii) Carboxylic acids do not give reactions of carbonyl group.(b) Write the chemical equations to illustrate the following name reactions:(i) Rosenmund reduction                      (ii) Cannizzaro’s reaction(c) Out of CH3CH2 – CO – CH2 – CH3 and CH3CH2 – CH2 – CO – CH3, which gives iodoform test?

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter22: Organic Chemistry
Section: Chapter Questions
Problem 28QAP: When the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction...
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(a) Account for the following :
(i) Cl – CH2COOH is a stronger acid than CH3COOH.
(ii) Carboxylic acids do not give reactions of carbonyl group.
(b) Write the chemical equations to illustrate the following name reactions:
(i) Rosenmund reduction                      (ii) Cannizzaro’s reaction
(c) Out of CH3CH2 – CO – CH2 – CH3 and CH3CH2 – CH2 – CO – CH3, which gives iodoform test?

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