Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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A 5.00×10−4 M solution of analyte is placed in a sample cell that has a pathlength of 1.00 cm. At a wavelength of 490 nm, the solution’s absorbance is 0.338. What is the analyte’s molar absorptivity at this wavelength?
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- The molar absorptivity constant of a particular chemical is 2.31 M/cm. Determine the concentration of a solution made from this chemical that has an absorbance of 0.521 with a cell path length of 1.04 cm.arrow_forward1.) Beer's Law can be used to find the concentration of a solution by measuring its absorbance. The law is given by ?=???A=ϵbC Where A is the absorbance, ?ϵ is the molar absorptivity, b is the pathlength of the light (the width of the sample cell), and C is the concentration of the solution. A student is analyzing a solution of a metal, and finds that the absorbance of the solution is 0.532. If ?=187 L⋅g−1⋅cm−1ϵ=187 L⋅g−1⋅cm−1 and ?=1 cmb=1 cm , what is the concentration of the metal in solution (in g/L)? * 352 * 2.84×10−32.84×10−3 * 2.84×10−22.84×10−2 * 96.8 2.) How many significant figures does the number 0.00358 have? Group of answer choices a.1 b.2 c.3 d.5 3.) A 10.00 mL solution of a certain food dye has a concentration of 1.47 g /L. What is the total mass of food dye in the solution? Report your answer with the correct number of significant figures.arrow_forwardSuppose that a solution has an absorbance of 0.250 at a wavelength of 450 nm. If the concentration of the solution is 22 μM, what is the value of the molar absorptivity? The data were taken with a standard 1-cm cuvette. molar absorptivity in (L cm^−1 mol^-1):arrow_forward
- A student prepared four standard solutions of (NH4)2Fe(SO4)2 and measured their absorbance at 505 nm. She created a calibration plot with the best-fit line of y = 9372 x + 0.0539. She measured the absorbance of her diluted unknown sample solution as (4.69x10^-1) nm. If she prepared her diluted sample solution by diluting 10.00 mL of the original solution to a total volume of 50.00 mL with deionized water, what is the concentration of Fe2+ in her original solution? Answer in units of M. Note: Your answer is assumed to be reduced to the highest power possible.arrow_forwardFe+3 (aq) + SCN – (aq) FeSCN +2 (aq) She mixes 4.00 mL of 2.00 mM SCN– and 5.00 mL of 2.00 mM Fe+3 ions, then diluting with 1.00mL of water to give a total volume of 10.00mL. She measures the absorbance of the solution asbeing 0.210. If she has previously calculated the molar absorbtivity constant (ε) of the product tobe 2583 cm–1 M–1, what is her best estimate for the K value for this reaction?arrow_forwardSuppose that a solution has an absorbance of 0.226 at a wavelength of 450 nm. If the concentration of the solution is 24 μM, what is the value of the molar absorptivity? The data were taken with a standard 1-cm cuvette.arrow_forward
- A never circulated 1975 penny with a mass of 3.00 g was dissolved in concentrated nitric acid, the resulting solution was then diluted to 50.0 mL with water. The weight percent copper in the penny was determined to be 94.7%. If the best-fit line for the Beer’s law plot was y=1.5x + 0.02, what is the absorbance of the penny solution?arrow_forwardFrom experimental data, a plot of absorbance (in arbitrary units, a.u.) at a wavelength of 630 nm (on the y-axis) was plotted against the concentration (in mg/L) of Cu2+ (on the x-axis) in known solutions and a linear relationship was found with an equation of y = 7.22x+0.05. If an unknown solution had an absorbance of 1.20 a.u. at a wavelength of 630 nm, what is its concentration of Cu2+?arrow_forwardCalculate the molar absorptivity of a solute when its measured absorbance is 1.050 with a concentration of 1.45 x 10-3 M. Assume the path length of the cell is 1.0 cm.arrow_forward
- The intensity of red light (680 nm) and sorted by a solution of green dye was found to be 1.99 V and the intensity of light when no dye was present (the blank) was found to be 2.69 V.What is the absorbable of the solution of green dye in three significant figuresarrow_forwardThe molar absorptivity of a compound at 500 nm wavelength is 252 M-1cm-1. Suppose one prepares a solution by dissolving 0.00140 moles of a solute in enough water to make a 500.0 mL solution. What would be the absorbance in a 7 .00 mm pathlength cell?arrow_forwardA solution with %T = 75.9% has an absorbance equal to: A = log (1 T) T= (% T 100)arrow_forward
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