A 1.0 g sample containing urea was dissolved in water and diluted in a 100.00 mL volumetric flask. 20.00 mL aliquot was mixed with 30.00 mL water and subjected to digestion with concentrated H2SO4. The ammonia produced is collected in 30.00 mL of 0.0500 M HCI and the excess acid is back titrated with 0.0500 M NAOH, requiring 6.80 mL. Calculate the weight percent urea [(NH2)2CO, FW=60.06 g/mol] in the sample.

Fundamentals Of Analytical Chemistry
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ISBN:9781285640686
Author:Skoog
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Chapter21: Potentiometry
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Problem 21.22QAP
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A 1.0 g sample containing urea was dissolved in water and diluted in a 100.00 mL volumetric flask.
20.00 mL aliquot was mixed with 30.00 mL water and subjected to digestion with concentrated
H2SO4. The ammonia produced is collected in 30.00 mL of 0.0500 M HCI and the excess acid is
back titrated with 0.0500 M NaOH, requiring 6.80 mL. Calculate the weight percent urea [(NH2)2CO,
FW=60.06 g/mol] in the sample.
Transcribed Image Text:A 1.0 g sample containing urea was dissolved in water and diluted in a 100.00 mL volumetric flask. 20.00 mL aliquot was mixed with 30.00 mL water and subjected to digestion with concentrated H2SO4. The ammonia produced is collected in 30.00 mL of 0.0500 M HCI and the excess acid is back titrated with 0.0500 M NaOH, requiring 6.80 mL. Calculate the weight percent urea [(NH2)2CO, FW=60.06 g/mol] in the sample.
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