A 0.6883 gram sample of impure potassium chlorate was treated with 45.00 mL of 0.1020 M Fe(NH4)2(SO4)2. The reaction is: ClO3-+6Fe2++6H+->Cl-+6Fe3++3H2O When the reaction was complete, the excess Fe(II) was back-titrated with 9.004 mL of 0.01734 M K2Cr2O7. Cr2O7-+6Fe2++14H+->2Cr3++6Fe3++7H2O Calculate the percent KClO3 (FW = 122.55) in the sample.

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter19: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 11E: Iron (II) can be oxidized to iron (III) by dichromate ion, which is reduced to chromium (III) in...
icon
Related questions
Question

A 0.6883 gram sample of impure potassium chlorate was treated with 45.00 mL of 0.1020 M Fe(NH4)2(SO4)2. The reaction is:

ClO3-+6Fe2++6H+->Cl-+6Fe3++3H2O

When the reaction was complete, the excess Fe(II) was back-titrated with 9.004 mL of 0.01734 M K2Cr2O7.

Cr2O7-+6Fe2++14H+->2Cr3++6Fe3++7H2O

Calculate the percent KClO3 (FW = 122.55) in the sample.

Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps with 4 images

Blurred answer
Knowledge Booster
Qualitative Analysis of Cations
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
General Chemistry - Standalone book (MindTap Cour…
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning