Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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9a.
Phosphoric acid, H3PO4, is a trivalent acid with pKs1 = 2.12, pKs2 = 7.21, and pK $3 =
12.37. Calculate how many milliliters of 1.50 M HCI should be added to 300 mL of 0.400 M
Na₂HPO4 to obtain a buffer solution with pH = 6.85.
9b.
To the resulting buffer solution in question 9a, 16.0 mL of 0.500 M NaOH is added. Calculate the
pH of the solution after this addition.
9c.
When ammonium hydrogen phosphate, (NH4)2HPO4, dissolves in water, the following
equilibrium is established:
NH +HPO +NH3+H,PO
K = 10-2.04
Based on the above equilibrium, calculate the concentrations of HPO and H₂PО in a 0.100
M solution of (NH4)2HPO4.
9d.
Calculate the pH of the solution in question 9c.
I
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Transcribed Image Text:9a. Phosphoric acid, H3PO4, is a trivalent acid with pKs1 = 2.12, pKs2 = 7.21, and pK $3 = 12.37. Calculate how many milliliters of 1.50 M HCI should be added to 300 mL of 0.400 M Na₂HPO4 to obtain a buffer solution with pH = 6.85. 9b. To the resulting buffer solution in question 9a, 16.0 mL of 0.500 M NaOH is added. Calculate the pH of the solution after this addition. 9c. When ammonium hydrogen phosphate, (NH4)2HPO4, dissolves in water, the following equilibrium is established: NH +HPO +NH3+H,PO K = 10-2.04 Based on the above equilibrium, calculate the concentrations of HPO and H₂PО in a 0.100 M solution of (NH4)2HPO4. 9d. Calculate the pH of the solution in question 9c. I
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