9.17 Select the member of each pair that shows the greater rate of SN2 reaction with KI in acetone. (a) ▸ Details (b) ▸ Details (c) (d) ▸ Details Br محمد or or Br ог ог Ха Br
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- 9.17 Select the member of each pair that shows the greater rate of S2 reaction with KI in acetone. (a) (c) Br or or (d) H H3C -Br or CH3 Br or Br Br2.84 For each of the following reactions, decide if (i) tendency toward minimum or products. in od (ii) tendency toward maximum randomness favors re- actants or products. gsmn o. bin m0 energy favors reactants b ginat aid n honnidel ad (d) CO(NH2)2 (aq) + H20 (1) M E0.0 CO2 (g) + 2NH3 (g) AH = +28.4 kkal (e) N204 (g) 2 2NO2 (g) AH= +14 kkål (f) 203 (g) 302 (g) AH = -68 kkal (g) 2NH3 (g) N (g) + 3H2 (g) AH = +22 kkal %3D %3D %3D %3D10.10 Radical Addition of HBr. Anti-Markovnikov Addition Which of the following mechanistic steps are considered initiation step(s) in the radical addition of HBr to an alkene? (1) + Br Bra (5) (2) ROOR -2 OR (3) Br+ Br + HBr OR +HB B + 01 02 03. 04 05 O2 and 4 O1 and 3 O3 and 5 Save for Later Br-Bri Br ROH + Br Br Submit Answ
- Q2/// Answer the followings: (4 Marks) 1) Which one more reactive to word nucleophilic substitution P- nitro toluene or O- ethyl toluene ? why?2.84 For each of the following reactions, decide if (i) tendency toward minimum or products. irg odi (ii) tendency toward maximum randomness favors re- actants or products. gsmn o.l bin mo energy favors reactants b ginat aid n honriide (d) CO(NH2)2 (aq) + H20 (1) 2 M ES0.0 CO2 (g) + 2NH3 (g) AH = +28.4 kkal (e) N204 (g) 2 2NO2 (g) AH= +14 kkal (f) 203 (g) 302 (g) AH = -68 kkal (g) 2NH3 (g) 2N (g) + 3H2 (g) AH = +22 kkal %3D %3D %3D2 Rank the following sets of compounds by the indicated criteria. A) Rate of reaction with Br/FeBrs OMe OMe OMe OMe NO2 A B C D slow fast B) Rate of reaction with NaOMe/MEOH CF3 ČF3 NO2 NO2 A B D. slow fast